N′-(5-Bromo-2-hydroxy­benzyl­idene)-3,4,5-trihydroxy­benzohydrazide dihydrate

The title compound, C(14)H(11)BrN(2)O(5)·2H(2)O, crystallizes as hydrogen-bonded sheets. The 2-hydr­oxy group on the benzyl­idene group forms an intra­molecular hydrogen bond to the N atom of the C=N double bond. The amino N atom is a hydrogen-bond donor to a water mol­ecule. The hydr­oxy group on t...

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Detalles Bibliográficos
Autores principales: Alhadi, Abeer A., Ali, Hapipah M., Puvaneswary, Subramaniam, Robinson, Ward T., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962201/
https://www.ncbi.nlm.nih.gov/pubmed/21203282
http://dx.doi.org/10.1107/S1600536808022708
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author Alhadi, Abeer A.
Ali, Hapipah M.
Puvaneswary, Subramaniam
Robinson, Ward T.
Ng, Seik Weng
author_facet Alhadi, Abeer A.
Ali, Hapipah M.
Puvaneswary, Subramaniam
Robinson, Ward T.
Ng, Seik Weng
author_sort Alhadi, Abeer A.
collection PubMed
description The title compound, C(14)H(11)BrN(2)O(5)·2H(2)O, crystallizes as hydrogen-bonded sheets. The 2-hydr­oxy group on the benzyl­idene group forms an intra­molecular hydrogen bond to the N atom of the C=N double bond. The amino N atom is a hydrogen-bond donor to a water mol­ecule. The hydr­oxy group on the benzohydrazide group is a hydrogen-bond donor to one acceptor site, whereas each water mol­ecule is a hydrogen-bond donor to two acceptor sites.
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spelling pubmed-29622012010-12-30 N′-(5-Bromo-2-hydroxy­benzyl­idene)-3,4,5-trihydroxy­benzohydrazide dihydrate Alhadi, Abeer A. Ali, Hapipah M. Puvaneswary, Subramaniam Robinson, Ward T. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(11)BrN(2)O(5)·2H(2)O, crystallizes as hydrogen-bonded sheets. The 2-hydr­oxy group on the benzyl­idene group forms an intra­molecular hydrogen bond to the N atom of the C=N double bond. The amino N atom is a hydrogen-bond donor to a water mol­ecule. The hydr­oxy group on the benzohydrazide group is a hydrogen-bond donor to one acceptor site, whereas each water mol­ecule is a hydrogen-bond donor to two acceptor sites. International Union of Crystallography 2008-07-23 /pmc/articles/PMC2962201/ /pubmed/21203282 http://dx.doi.org/10.1107/S1600536808022708 Text en © Alhadi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Alhadi, Abeer A.
Ali, Hapipah M.
Puvaneswary, Subramaniam
Robinson, Ward T.
Ng, Seik Weng
N′-(5-Bromo-2-hydroxy­benzyl­idene)-3,4,5-trihydroxy­benzohydrazide dihydrate
title N′-(5-Bromo-2-hydroxy­benzyl­idene)-3,4,5-trihydroxy­benzohydrazide dihydrate
title_full N′-(5-Bromo-2-hydroxy­benzyl­idene)-3,4,5-trihydroxy­benzohydrazide dihydrate
title_fullStr N′-(5-Bromo-2-hydroxy­benzyl­idene)-3,4,5-trihydroxy­benzohydrazide dihydrate
title_full_unstemmed N′-(5-Bromo-2-hydroxy­benzyl­idene)-3,4,5-trihydroxy­benzohydrazide dihydrate
title_short N′-(5-Bromo-2-hydroxy­benzyl­idene)-3,4,5-trihydroxy­benzohydrazide dihydrate
title_sort n′-(5-bromo-2-hydroxy­benzyl­idene)-3,4,5-trihydroxy­benzohydrazide dihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962201/
https://www.ncbi.nlm.nih.gov/pubmed/21203282
http://dx.doi.org/10.1107/S1600536808022708
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