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N-(2,6-Dimethylphenyl)-2-methylbenzamide
In the title molecule, C(16)H(17)NO, the N—H and C=O groups are in the antiperiplanar conformation that has been observed in related compounds. Furthermore, the conformation of the C=O group with respect to the methyl substituent in the 2-methylphenyl ring is syn, as has also been observed in rel...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962217/ https://www.ncbi.nlm.nih.gov/pubmed/21203298 http://dx.doi.org/10.1107/S160053680802309X |
Sumario: | In the title molecule, C(16)H(17)NO, the N—H and C=O groups are in the antiperiplanar conformation that has been observed in related compounds. Furthermore, the conformation of the C=O group with respect to the methyl substituent in the 2-methylphenyl ring is syn, as has also been observed in related structures. The amide group makes dihedral angles of 50.3 (3) and 64.6 (3)° with the 2-methylphenyl and 2,6-dimethylphenyl rings, respectively, while the angle between the planes of the two rings is 14.26 (7)°. The molecules are packed into chains via N—H⋯O hydrogen bonds. An intramolecular C—H⋯O hydrogen bond is also observed. |
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