N-(2,6-Dimethyl­phen­yl)-2-methyl­benzamide

In the title mol­ecule, C(16)H(17)NO, the N—H and C=O groups are in the anti­periplanar conformation that has been observed in related compounds. Furthermore, the conformation of the C=O group with respect to the methyl substituent in the 2-methyl­phenyl ring is syn, as has also been observed in rel...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Sowmya, B. P., Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962217/
https://www.ncbi.nlm.nih.gov/pubmed/21203298
http://dx.doi.org/10.1107/S160053680802309X
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author Gowda, B. Thimme
Foro, Sabine
Sowmya, B. P.
Fuess, Hartmut
author_facet Gowda, B. Thimme
Foro, Sabine
Sowmya, B. P.
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description In the title mol­ecule, C(16)H(17)NO, the N—H and C=O groups are in the anti­periplanar conformation that has been observed in related compounds. Furthermore, the conformation of the C=O group with respect to the methyl substituent in the 2-methyl­phenyl ring is syn, as has also been observed in related structures. The amide group makes dihedral angles of 50.3 (3) and 64.6 (3)° with the 2-methyl­phenyl and 2,6-dimethyl­phenyl rings, respectively, while the angle between the planes of the two rings is 14.26 (7)°. The mol­ecules are packed into chains via N—H⋯O hydrogen bonds. An intramolecular C—H⋯O hydrogen bond is also observed.
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spelling pubmed-29622172010-12-30 N-(2,6-Dimethyl­phen­yl)-2-methyl­benzamide Gowda, B. Thimme Foro, Sabine Sowmya, B. P. Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(16)H(17)NO, the N—H and C=O groups are in the anti­periplanar conformation that has been observed in related compounds. Furthermore, the conformation of the C=O group with respect to the methyl substituent in the 2-methyl­phenyl ring is syn, as has also been observed in related structures. The amide group makes dihedral angles of 50.3 (3) and 64.6 (3)° with the 2-methyl­phenyl and 2,6-dimethyl­phenyl rings, respectively, while the angle between the planes of the two rings is 14.26 (7)°. The mol­ecules are packed into chains via N—H⋯O hydrogen bonds. An intramolecular C—H⋯O hydrogen bond is also observed. International Union of Crystallography 2008-07-26 /pmc/articles/PMC2962217/ /pubmed/21203298 http://dx.doi.org/10.1107/S160053680802309X Text en © Gowda et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Foro, Sabine
Sowmya, B. P.
Fuess, Hartmut
N-(2,6-Dimethyl­phen­yl)-2-methyl­benzamide
title N-(2,6-Dimethyl­phen­yl)-2-methyl­benzamide
title_full N-(2,6-Dimethyl­phen­yl)-2-methyl­benzamide
title_fullStr N-(2,6-Dimethyl­phen­yl)-2-methyl­benzamide
title_full_unstemmed N-(2,6-Dimethyl­phen­yl)-2-methyl­benzamide
title_short N-(2,6-Dimethyl­phen­yl)-2-methyl­benzamide
title_sort n-(2,6-dimethyl­phen­yl)-2-methyl­benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962217/
https://www.ncbi.nlm.nih.gov/pubmed/21203298
http://dx.doi.org/10.1107/S160053680802309X
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AT forosabine n26dimethylphenyl2methylbenzamide
AT sowmyabp n26dimethylphenyl2methylbenzamide
AT fuesshartmut n26dimethylphenyl2methylbenzamide

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