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(R)-(+)-3-Hydroxy-2-methoxycarbonyl-8-methyl-8-azoniabicyclo[3.2.1]octane l-bitartrate
(RS)-(±)-2-Methoxycarbonyl-3-tropinone is an important intermediate for the preparation of cocaine and its derivatives. The molecule in the title compound, C(10)H(16)NO(3) (+)·C(4)H(5)O(6) (−), is present as the enol tautomer. The six-membered ring adopts a half boat conformation, and the five-mem...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962227/ https://www.ncbi.nlm.nih.gov/pubmed/21203339 http://dx.doi.org/10.1107/S1600536808023532 |
| Sumario: | (RS)-(±)-2-Methoxycarbonyl-3-tropinone is an important intermediate for the preparation of cocaine and its derivatives. The molecule in the title compound, C(10)H(16)NO(3) (+)·C(4)H(5)O(6) (−), is present as the enol tautomer. The six-membered ring adopts a half boat conformation, and the five-membered ring a slightly distorted envelope conformation. There are intra- and intermolecular hydrogen bonds involving the hydroxyl, carboxyl groups and quaternary ammonium groups. |
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