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Dichlorido[1-(1,10-phenanthrolin-2-yl)-2-pyridone]cadmium(II)
In the title mononuclear complex, [CdCl(2)(C(17)H(11)N(3)O)], the Cd(II) ion assumes a distorted trigonal–bipyramidal coordination geometry. The pyridone plane is twisted out of the 1,10-phenanthroline mean plane by 43.8 (3)°. In the crystal structure, short intermolecular distances [3.627 (4)–3.67...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962234/ https://www.ncbi.nlm.nih.gov/pubmed/21203087 http://dx.doi.org/10.1107/S1600536808019740 |
| _version_ | 1782189171903823872 |
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| author | Li, Jin-Min |
| author_facet | Li, Jin-Min |
| author_sort | Li, Jin-Min |
| collection | PubMed |
| description | In the title mononuclear complex, [CdCl(2)(C(17)H(11)N(3)O)], the Cd(II) ion assumes a distorted trigonal–bipyramidal coordination geometry. The pyridone plane is twisted out of the 1,10-phenanthroline mean plane by 43.8 (3)°. In the crystal structure, short intermolecular distances [3.627 (4)–3.671 (4) Å] between the centroids of the six- and five-membered Cd-containing rings suggest the existence of π–π interactions, which link the molecules into stacks along the a axis. |
| format | Text |
| id | pubmed-2962234 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29622342010-12-30 Dichlorido[1-(1,10-phenanthrolin-2-yl)-2-pyridone]cadmium(II) Li, Jin-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear complex, [CdCl(2)(C(17)H(11)N(3)O)], the Cd(II) ion assumes a distorted trigonal–bipyramidal coordination geometry. The pyridone plane is twisted out of the 1,10-phenanthroline mean plane by 43.8 (3)°. In the crystal structure, short intermolecular distances [3.627 (4)–3.671 (4) Å] between the centroids of the six- and five-membered Cd-containing rings suggest the existence of π–π interactions, which link the molecules into stacks along the a axis. International Union of Crystallography 2008-07-05 /pmc/articles/PMC2962234/ /pubmed/21203087 http://dx.doi.org/10.1107/S1600536808019740 Text en © Jin-Min Li 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Jin-Min Dichlorido[1-(1,10-phenanthrolin-2-yl)-2-pyridone]cadmium(II) |
| title | Dichlorido[1-(1,10-phenanthrolin-2-yl)-2-pyridone]cadmium(II) |
| title_full | Dichlorido[1-(1,10-phenanthrolin-2-yl)-2-pyridone]cadmium(II) |
| title_fullStr | Dichlorido[1-(1,10-phenanthrolin-2-yl)-2-pyridone]cadmium(II) |
| title_full_unstemmed | Dichlorido[1-(1,10-phenanthrolin-2-yl)-2-pyridone]cadmium(II) |
| title_short | Dichlorido[1-(1,10-phenanthrolin-2-yl)-2-pyridone]cadmium(II) |
| title_sort | dichlorido[1-(1,10-phenanthrolin-2-yl)-2-pyridone]cadmium(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962234/ https://www.ncbi.nlm.nih.gov/pubmed/21203087 http://dx.doi.org/10.1107/S1600536808019740 |
| work_keys_str_mv | AT lijinmin dichlorido1110phenanthrolin2yl2pyridonecadmiumii |