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catena-Poly[[hexa­kis(μ-4-methyl­benzoato)-κ(2) O,O′;κ(15) O,O′:O-trieuropium(III)]-tris­(μ-4-methyl­benzoato)-κ(2) O,O′;κ(6) O,O′:O]

The title europium(III) carboxyl­ate, [Eu(3)(C(8)H(7)O(2))(9)](n), has three independent Eu atoms, two of which are eight-coordinate in a square-anti­prismatic coordination geometry, whereas the third is nine-coordinate in a tricapped trigonal-prismatic coordination geometry. The metal atoms are lin...

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Detalles Bibliográficos
Autores principales: Zhang, Chao-Hua, Hong, Peng-Zhi, Song, Wen-Dong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962240/
https://www.ncbi.nlm.nih.gov/pubmed/21203042
http://dx.doi.org/10.1107/S1600536808022836
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author Zhang, Chao-Hua
Hong, Peng-Zhi
Song, Wen-Dong
author_facet Zhang, Chao-Hua
Hong, Peng-Zhi
Song, Wen-Dong
author_sort Zhang, Chao-Hua
collection PubMed
description The title europium(III) carboxyl­ate, [Eu(3)(C(8)H(7)O(2))(9)](n), has three independent Eu atoms, two of which are eight-coordinate in a square-anti­prismatic coordination geometry, whereas the third is nine-coordinate in a tricapped trigonal-prismatic coordination geometry. The metal atoms are linked by two bidentate and seven tridentate methyl­benzoate groups into a linear chain running along the b-axis direction.
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spelling pubmed-29622402010-12-30 catena-Poly[[hexa­kis(μ-4-methyl­benzoato)-κ(2) O,O′;κ(15) O,O′:O-trieuropium(III)]-tris­(μ-4-methyl­benzoato)-κ(2) O,O′;κ(6) O,O′:O] Zhang, Chao-Hua Hong, Peng-Zhi Song, Wen-Dong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title europium(III) carboxyl­ate, [Eu(3)(C(8)H(7)O(2))(9)](n), has three independent Eu atoms, two of which are eight-coordinate in a square-anti­prismatic coordination geometry, whereas the third is nine-coordinate in a tricapped trigonal-prismatic coordination geometry. The metal atoms are linked by two bidentate and seven tridentate methyl­benzoate groups into a linear chain running along the b-axis direction. International Union of Crystallography 2008-07-23 /pmc/articles/PMC2962240/ /pubmed/21203042 http://dx.doi.org/10.1107/S1600536808022836 Text en © Zhang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Chao-Hua
Hong, Peng-Zhi
Song, Wen-Dong
catena-Poly[[hexa­kis(μ-4-methyl­benzoato)-κ(2) O,O′;κ(15) O,O′:O-trieuropium(III)]-tris­(μ-4-methyl­benzoato)-κ(2) O,O′;κ(6) O,O′:O]
title catena-Poly[[hexa­kis(μ-4-methyl­benzoato)-κ(2) O,O′;κ(15) O,O′:O-trieuropium(III)]-tris­(μ-4-methyl­benzoato)-κ(2) O,O′;κ(6) O,O′:O]
title_full catena-Poly[[hexa­kis(μ-4-methyl­benzoato)-κ(2) O,O′;κ(15) O,O′:O-trieuropium(III)]-tris­(μ-4-methyl­benzoato)-κ(2) O,O′;κ(6) O,O′:O]
title_fullStr catena-Poly[[hexa­kis(μ-4-methyl­benzoato)-κ(2) O,O′;κ(15) O,O′:O-trieuropium(III)]-tris­(μ-4-methyl­benzoato)-κ(2) O,O′;κ(6) O,O′:O]
title_full_unstemmed catena-Poly[[hexa­kis(μ-4-methyl­benzoato)-κ(2) O,O′;κ(15) O,O′:O-trieuropium(III)]-tris­(μ-4-methyl­benzoato)-κ(2) O,O′;κ(6) O,O′:O]
title_short catena-Poly[[hexa­kis(μ-4-methyl­benzoato)-κ(2) O,O′;κ(15) O,O′:O-trieuropium(III)]-tris­(μ-4-methyl­benzoato)-κ(2) O,O′;κ(6) O,O′:O]
title_sort catena-poly[[hexa­kis(μ-4-methyl­benzoato)-κ(2) o,o′;κ(15) o,o′:o-trieuropium(iii)]-tris­(μ-4-methyl­benzoato)-κ(2) o,o′;κ(6) o,o′:o]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962240/
https://www.ncbi.nlm.nih.gov/pubmed/21203042
http://dx.doi.org/10.1107/S1600536808022836
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