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catena-Poly[zinc(II)-bis[μ-5-(2-aminophenyl)tetrazolato]-κ(3) N (1),N (5):N (2);κ(3) N (2):N (1),N (5)]
The polymeric title compound, [Zn(C(7)H(6)N(5))(2)](n), was synthesized by the hydrothermal reaction of Zn(NO(3))(2) with 2-aminobenzonitrile in the presence of NaN(3). The zinc(II) metal centre displays a distorted octahedral coordination environment provided by N atoms of two bidentate chelatin...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962247/ https://www.ncbi.nlm.nih.gov/pubmed/21203024 http://dx.doi.org/10.1107/S1600536808021946 |
Sumario: | The polymeric title compound, [Zn(C(7)H(6)N(5))(2)](n), was synthesized by the hydrothermal reaction of Zn(NO(3))(2) with 2-aminobenzonitrile in the presence of NaN(3). The zinc(II) metal centre displays a distorted octahedral coordination environment provided by N atoms of two bidentate chelating and two monodentate 5-(2-aminophenyl)tetrazolate ligands. These ligands act as bridges, linking adjacent Zn atoms into polymeric criss-crossed chains parallel to the [110] and [[Image: see text]10] directions. Intrachain N—H⋯N hydrogen-bonding interactions are observed. |
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