catena-Poly[zinc(II)-bis­[μ-5-(2-amino­phenyl)tetra­zolato]-κ(3) N (1),N (5):N (2);κ(3) N (2):N (1),N (5)]

The polymeric title compound, [Zn(C(7)H(6)N(5))(2)](n), was synthesized by the hydro­thermal reaction of Zn(NO(3))(2) with 2-amino­benzonitrile in the presence of NaN(3). The zinc(II) metal centre displays a distorted octa­hedral coordination environment provided by N atoms of two bidentate chelatin...

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Detalles Bibliográficos
Autor principal: Wen, Xiao-Chun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962247/
https://www.ncbi.nlm.nih.gov/pubmed/21203024
http://dx.doi.org/10.1107/S1600536808021946
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author Wen, Xiao-Chun
author_facet Wen, Xiao-Chun
author_sort Wen, Xiao-Chun
collection PubMed
description The polymeric title compound, [Zn(C(7)H(6)N(5))(2)](n), was synthesized by the hydro­thermal reaction of Zn(NO(3))(2) with 2-amino­benzonitrile in the presence of NaN(3). The zinc(II) metal centre displays a distorted octa­hedral coordination environment provided by N atoms of two bidentate chelating and two monodentate 5-(2-amino­phen­yl)tetra­zolate ligands. These ligands act as bridges, linking adjacent Zn atoms into polymeric criss-crossed chains parallel to the [110] and [[Image: see text]10] directions. Intra­chain N—H⋯N hydrogen-bonding inter­actions are observed.
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spelling pubmed-29622472010-12-30 catena-Poly[zinc(II)-bis­[μ-5-(2-amino­phenyl)tetra­zolato]-κ(3) N (1),N (5):N (2);κ(3) N (2):N (1),N (5)] Wen, Xiao-Chun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The polymeric title compound, [Zn(C(7)H(6)N(5))(2)](n), was synthesized by the hydro­thermal reaction of Zn(NO(3))(2) with 2-amino­benzonitrile in the presence of NaN(3). The zinc(II) metal centre displays a distorted octa­hedral coordination environment provided by N atoms of two bidentate chelating and two monodentate 5-(2-amino­phen­yl)tetra­zolate ligands. These ligands act as bridges, linking adjacent Zn atoms into polymeric criss-crossed chains parallel to the [110] and [[Image: see text]10] directions. Intra­chain N—H⋯N hydrogen-bonding inter­actions are observed. International Union of Crystallography 2008-07-16 /pmc/articles/PMC2962247/ /pubmed/21203024 http://dx.doi.org/10.1107/S1600536808021946 Text en © Xiao-Chun Wen 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wen, Xiao-Chun
catena-Poly[zinc(II)-bis­[μ-5-(2-amino­phenyl)tetra­zolato]-κ(3) N (1),N (5):N (2);κ(3) N (2):N (1),N (5)]
title catena-Poly[zinc(II)-bis­[μ-5-(2-amino­phenyl)tetra­zolato]-κ(3) N (1),N (5):N (2);κ(3) N (2):N (1),N (5)]
title_full catena-Poly[zinc(II)-bis­[μ-5-(2-amino­phenyl)tetra­zolato]-κ(3) N (1),N (5):N (2);κ(3) N (2):N (1),N (5)]
title_fullStr catena-Poly[zinc(II)-bis­[μ-5-(2-amino­phenyl)tetra­zolato]-κ(3) N (1),N (5):N (2);κ(3) N (2):N (1),N (5)]
title_full_unstemmed catena-Poly[zinc(II)-bis­[μ-5-(2-amino­phenyl)tetra­zolato]-κ(3) N (1),N (5):N (2);κ(3) N (2):N (1),N (5)]
title_short catena-Poly[zinc(II)-bis­[μ-5-(2-amino­phenyl)tetra­zolato]-κ(3) N (1),N (5):N (2);κ(3) N (2):N (1),N (5)]
title_sort catena-poly[zinc(ii)-bis­[μ-5-(2-amino­phenyl)tetra­zolato]-κ(3) n (1),n (5):n (2);κ(3) n (2):n (1),n (5)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962247/
https://www.ncbi.nlm.nih.gov/pubmed/21203024
http://dx.doi.org/10.1107/S1600536808021946
work_keys_str_mv AT wenxiaochun catenapolyzinciibism52aminophenyltetrazolatok3n1n5n2k3n2n1n5

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