P,P-Diphenyl-N-(1,1,2,2-tetra­phenyl-1λ(5)-diphosphanyl­idene)phosphinous amide

The title compound, C(36)H(30)NP(3), a structural isomer of tris­(diphenyl­phosphino)amine, was unexpectedly isolated as the sole phospho­rus-containing product from the reaction of Mg[N(PPh(2))(2)](2)(THF)(2) (THF is tetra­hydro­furan) with CO(2). Its identity was confirmed by (31)P NMR spectroscop...

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Autores principales: Dickie, Diane A., Kemp, Richard A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962250/
https://www.ncbi.nlm.nih.gov/pubmed/21203164
http://dx.doi.org/10.1107/S1600536808020412
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author Dickie, Diane A.
Kemp, Richard A.
author_facet Dickie, Diane A.
Kemp, Richard A.
author_sort Dickie, Diane A.
collection PubMed
description The title compound, C(36)H(30)NP(3), a structural isomer of tris­(diphenyl­phosphino)amine, was unexpectedly isolated as the sole phospho­rus-containing product from the reaction of Mg[N(PPh(2))(2)](2)(THF)(2) (THF is tetra­hydro­furan) with CO(2). Its identity was confirmed by (31)P NMR spectroscopy and single-crystal X-ray diffraction. The geometry at the two P(III) atoms is trigonal pyramidal, while the P(V) atom adopts a distorted tetrahedral geometry.
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spelling pubmed-29622502010-12-30 P,P-Diphenyl-N-(1,1,2,2-tetra­phenyl-1λ(5)-diphosphanyl­idene)phosphinous amide Dickie, Diane A. Kemp, Richard A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(36)H(30)NP(3), a structural isomer of tris­(diphenyl­phosphino)amine, was unexpectedly isolated as the sole phospho­rus-containing product from the reaction of Mg[N(PPh(2))(2)](2)(THF)(2) (THF is tetra­hydro­furan) with CO(2). Its identity was confirmed by (31)P NMR spectroscopy and single-crystal X-ray diffraction. The geometry at the two P(III) atoms is trigonal pyramidal, while the P(V) atom adopts a distorted tetrahedral geometry. International Union of Crystallography 2008-07-09 /pmc/articles/PMC2962250/ /pubmed/21203164 http://dx.doi.org/10.1107/S1600536808020412 Text en © Dickie and Kemp 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Dickie, Diane A.
Kemp, Richard A.
P,P-Diphenyl-N-(1,1,2,2-tetra­phenyl-1λ(5)-diphosphanyl­idene)phosphinous amide
title P,P-Diphenyl-N-(1,1,2,2-tetra­phenyl-1λ(5)-diphosphanyl­idene)phosphinous amide
title_full P,P-Diphenyl-N-(1,1,2,2-tetra­phenyl-1λ(5)-diphosphanyl­idene)phosphinous amide
title_fullStr P,P-Diphenyl-N-(1,1,2,2-tetra­phenyl-1λ(5)-diphosphanyl­idene)phosphinous amide
title_full_unstemmed P,P-Diphenyl-N-(1,1,2,2-tetra­phenyl-1λ(5)-diphosphanyl­idene)phosphinous amide
title_short P,P-Diphenyl-N-(1,1,2,2-tetra­phenyl-1λ(5)-diphosphanyl­idene)phosphinous amide
title_sort p,p-diphenyl-n-(1,1,2,2-tetra­phenyl-1λ(5)-diphosphanyl­idene)phosphinous amide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2962250/
https://www.ncbi.nlm.nih.gov/pubmed/21203164
http://dx.doi.org/10.1107/S1600536808020412
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