Dicaesium magnesium bis­(dihydrogen phosphate(V)) dihydrate

The title compound, Cs(2)Mg(H(2)P(2)O(7))(2)·2H(2)O, is isostructural with the related known isoformular phosphates. The crystal framework consists of corner-sharing MgO(6) and H(2)P(2)O(7) polyhedra, leading to tunnels parallel to the b-axis direction in which Cs(+) ions are located. The H(2)P(2)O(...

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Autores principales: Essehli, Rachid, El Bali, Brahim, Lachkar, Mohammed, Bolte, Michael
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967844/
https://www.ncbi.nlm.nih.gov/pubmed/21581465
http://dx.doi.org/10.1107/S1600536808042384
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author Essehli, Rachid
El Bali, Brahim
Lachkar, Mohammed
Bolte, Michael
author_facet Essehli, Rachid
El Bali, Brahim
Lachkar, Mohammed
Bolte, Michael
author_sort Essehli, Rachid
collection PubMed
description The title compound, Cs(2)Mg(H(2)P(2)O(7))(2)·2H(2)O, is isostructural with the related known isoformular phosphates. The crystal framework consists of corner-sharing MgO(6) and H(2)P(2)O(7) polyhedra, leading to tunnels parallel to the b-axis direction in which Cs(+) ions are located. The H(2)P(2)O(7) unit shows a bent eclipsed conformation. The Mg(2+) ion lies on an inversion center. The water molecules form hydrogen bonds to O atoms of two different dihydrogenphosphate ions, which are further hydrogen bonded to symmetry-equivalent dihydrogenphosphate ions.
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spelling pubmed-29678442010-12-30 Dicaesium magnesium bis­(dihydrogen phosphate(V)) dihydrate Essehli, Rachid El Bali, Brahim Lachkar, Mohammed Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, Cs(2)Mg(H(2)P(2)O(7))(2)·2H(2)O, is isostructural with the related known isoformular phosphates. The crystal framework consists of corner-sharing MgO(6) and H(2)P(2)O(7) polyhedra, leading to tunnels parallel to the b-axis direction in which Cs(+) ions are located. The H(2)P(2)O(7) unit shows a bent eclipsed conformation. The Mg(2+) ion lies on an inversion center. The water molecules form hydrogen bonds to O atoms of two different dihydrogenphosphate ions, which are further hydrogen bonded to symmetry-equivalent dihydrogenphosphate ions. International Union of Crystallography 2008-12-17 /pmc/articles/PMC2967844/ /pubmed/21581465 http://dx.doi.org/10.1107/S1600536808042384 Text en © Essehli et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Essehli, Rachid
El Bali, Brahim
Lachkar, Mohammed
Bolte, Michael
Dicaesium magnesium bis­(dihydrogen phosphate(V)) dihydrate
title Dicaesium magnesium bis­(dihydrogen phosphate(V)) dihydrate
title_full Dicaesium magnesium bis­(dihydrogen phosphate(V)) dihydrate
title_fullStr Dicaesium magnesium bis­(dihydrogen phosphate(V)) dihydrate
title_full_unstemmed Dicaesium magnesium bis­(dihydrogen phosphate(V)) dihydrate
title_short Dicaesium magnesium bis­(dihydrogen phosphate(V)) dihydrate
title_sort dicaesium magnesium bis­(dihydrogen phosphate(v)) dihydrate
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967844/
https://www.ncbi.nlm.nih.gov/pubmed/21581465
http://dx.doi.org/10.1107/S1600536808042384
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AT elbalibrahim dicaesiummagnesiumbisdihydrogenphosphatevdihydrate
AT lachkarmohammed dicaesiummagnesiumbisdihydrogenphosphatevdihydrate
AT boltemichael dicaesiummagnesiumbisdihydrogenphosphatevdihydrate

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