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Bis(N,N-dimethyl­formamide-κO)bis­(2,4,6-trinitro­phenolato-κ(2) O (1),O (2))copper(II)

The mol­ecule of the title complex, [Cu(C(6)H(2)N(3)O(7))(2)(C(3)H(7)NO)(2)], is disposed about a crystallographic centre of symmetry. The Cu(II) cation is six-coordinated by two phenolate O atoms and two ortho-nitro O atoms of two picrate units and by two carbonyl O atoms from two coordinated dimet...

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Detalles Bibliográficos
Autores principales: Li, Bai-Yu, Tong, Jun-Feng, Dong, Wen-Kui, Yao, Jian, Wu, Jian-Chao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967846/
https://www.ncbi.nlm.nih.gov/pubmed/21581467
http://dx.doi.org/10.1107/S1600536808039846
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author Li, Bai-Yu
Tong, Jun-Feng
Dong, Wen-Kui
Yao, Jian
Wu, Jian-Chao
author_facet Li, Bai-Yu
Tong, Jun-Feng
Dong, Wen-Kui
Yao, Jian
Wu, Jian-Chao
author_sort Li, Bai-Yu
collection PubMed
description The mol­ecule of the title complex, [Cu(C(6)H(2)N(3)O(7))(2)(C(3)H(7)NO)(2)], is disposed about a crystallographic centre of symmetry. The Cu(II) cation is six-coordinated by two phenolate O atoms and two ortho-nitro O atoms of two picrate units and by two carbonyl O atoms from two coordinated dimethyl­formamide mol­ecules, forming a distorted octa­hedral geometry.
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spelling pubmed-29678462010-12-30 Bis(N,N-dimethyl­formamide-κO)bis­(2,4,6-trinitro­phenolato-κ(2) O (1),O (2))copper(II) Li, Bai-Yu Tong, Jun-Feng Dong, Wen-Kui Yao, Jian Wu, Jian-Chao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mol­ecule of the title complex, [Cu(C(6)H(2)N(3)O(7))(2)(C(3)H(7)NO)(2)], is disposed about a crystallographic centre of symmetry. The Cu(II) cation is six-coordinated by two phenolate O atoms and two ortho-nitro O atoms of two picrate units and by two carbonyl O atoms from two coordinated dimethyl­formamide mol­ecules, forming a distorted octa­hedral geometry. International Union of Crystallography 2008-12-03 /pmc/articles/PMC2967846/ /pubmed/21581467 http://dx.doi.org/10.1107/S1600536808039846 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Bai-Yu
Tong, Jun-Feng
Dong, Wen-Kui
Yao, Jian
Wu, Jian-Chao
Bis(N,N-dimethyl­formamide-κO)bis­(2,4,6-trinitro­phenolato-κ(2) O (1),O (2))copper(II)
title Bis(N,N-dimethyl­formamide-κO)bis­(2,4,6-trinitro­phenolato-κ(2) O (1),O (2))copper(II)
title_full Bis(N,N-dimethyl­formamide-κO)bis­(2,4,6-trinitro­phenolato-κ(2) O (1),O (2))copper(II)
title_fullStr Bis(N,N-dimethyl­formamide-κO)bis­(2,4,6-trinitro­phenolato-κ(2) O (1),O (2))copper(II)
title_full_unstemmed Bis(N,N-dimethyl­formamide-κO)bis­(2,4,6-trinitro­phenolato-κ(2) O (1),O (2))copper(II)
title_short Bis(N,N-dimethyl­formamide-κO)bis­(2,4,6-trinitro­phenolato-κ(2) O (1),O (2))copper(II)
title_sort bis(n,n-dimethyl­formamide-κo)bis­(2,4,6-trinitro­phenolato-κ(2) o (1),o (2))copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967846/
https://www.ncbi.nlm.nih.gov/pubmed/21581467
http://dx.doi.org/10.1107/S1600536808039846
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