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(2,2′-Bipyridine-κ(2) N,N′)iodido(piperidine-1-carbodithioato-κ(2) S,S′)copper(II)
In the title compound, [Cu(C(6)H(10)NS(2))I(C(10)H(8)N(2))], the Cu(II) ion is coordinated by one iodide ion, two N atoms of the bipyridine ligand and two S atoms from the piperidinecarbodithioate ligand in a distorted square-pyramidal environment. π–π stacking interactions, with centroid–centroi...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967849/ https://www.ncbi.nlm.nih.gov/pubmed/21581529 http://dx.doi.org/10.1107/S1600536808039901 |
Sumario: | In the title compound, [Cu(C(6)H(10)NS(2))I(C(10)H(8)N(2))], the Cu(II) ion is coordinated by one iodide ion, two N atoms of the bipyridine ligand and two S atoms from the piperidinecarbodithioate ligand in a distorted square-pyramidal environment. π–π stacking interactions, with centroid–centroid distances of 3.643 (4) Å, between pyridyl rings of the bipyridyl ligands of neighbouring molecules lead to chains propagating parallel to the a axis. |
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