Cargando…
(2,2′-Bipyridine-κ(2) N,N′)iodido(piperidine-1-carbodithioato-κ(2) S,S′)copper(II)
In the title compound, [Cu(C(6)H(10)NS(2))I(C(10)H(8)N(2))], the Cu(II) ion is coordinated by one iodide ion, two N atoms of the bipyridine ligand and two S atoms from the piperidinecarbodithioate ligand in a distorted square-pyramidal environment. π–π stacking interactions, with centroid–centroi...
Autor principal: | |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967849/ https://www.ncbi.nlm.nih.gov/pubmed/21581529 http://dx.doi.org/10.1107/S1600536808039901 |
_version_ | 1782189709329432576 |
---|---|
author | Fan, Le-Qing |
author_facet | Fan, Le-Qing |
author_sort | Fan, Le-Qing |
collection | PubMed |
description | In the title compound, [Cu(C(6)H(10)NS(2))I(C(10)H(8)N(2))], the Cu(II) ion is coordinated by one iodide ion, two N atoms of the bipyridine ligand and two S atoms from the piperidinecarbodithioate ligand in a distorted square-pyramidal environment. π–π stacking interactions, with centroid–centroid distances of 3.643 (4) Å, between pyridyl rings of the bipyridyl ligands of neighbouring molecules lead to chains propagating parallel to the a axis. |
format | Text |
id | pubmed-2967849 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29678492010-12-30 (2,2′-Bipyridine-κ(2) N,N′)iodido(piperidine-1-carbodithioato-κ(2) S,S′)copper(II) Fan, Le-Qing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(6)H(10)NS(2))I(C(10)H(8)N(2))], the Cu(II) ion is coordinated by one iodide ion, two N atoms of the bipyridine ligand and two S atoms from the piperidinecarbodithioate ligand in a distorted square-pyramidal environment. π–π stacking interactions, with centroid–centroid distances of 3.643 (4) Å, between pyridyl rings of the bipyridyl ligands of neighbouring molecules lead to chains propagating parallel to the a axis. International Union of Crystallography 2008-12-03 /pmc/articles/PMC2967849/ /pubmed/21581529 http://dx.doi.org/10.1107/S1600536808039901 Text en © Le-Qing Fan 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Fan, Le-Qing (2,2′-Bipyridine-κ(2) N,N′)iodido(piperidine-1-carbodithioato-κ(2) S,S′)copper(II) |
title | (2,2′-Bipyridine-κ(2)
N,N′)iodido(piperidine-1-carbodithioato-κ(2)
S,S′)copper(II) |
title_full | (2,2′-Bipyridine-κ(2)
N,N′)iodido(piperidine-1-carbodithioato-κ(2)
S,S′)copper(II) |
title_fullStr | (2,2′-Bipyridine-κ(2)
N,N′)iodido(piperidine-1-carbodithioato-κ(2)
S,S′)copper(II) |
title_full_unstemmed | (2,2′-Bipyridine-κ(2)
N,N′)iodido(piperidine-1-carbodithioato-κ(2)
S,S′)copper(II) |
title_short | (2,2′-Bipyridine-κ(2)
N,N′)iodido(piperidine-1-carbodithioato-κ(2)
S,S′)copper(II) |
title_sort | (2,2′-bipyridine-κ(2)
n,n′)iodido(piperidine-1-carbodithioato-κ(2)
s,s′)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967849/ https://www.ncbi.nlm.nih.gov/pubmed/21581529 http://dx.doi.org/10.1107/S1600536808039901 |
work_keys_str_mv | AT fanleqing 22bipyridinek2nniodidopiperidine1carbodithioatok2sscopperii |