Tris(2,2′-bipyridine-κ(2) N,N′)cadmium(II) bis­(perchlorate) hemihydrate

The asymmetric unit of the title compound, [Cd(C(10)H(8)N(2))(3)](ClO(4))(2)·0.5H(2)O, consists of one complex [Cd(bpy)(3)](2+) cation (bpy = 2,2′-bipyridine), two perchlorate anions and one water molecule with half-occupancy. The central cadmium(II) ion is bound to six N atoms from three bpy ligand...

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Detalles Bibliográficos
Autores principales: Zhang, Weiguang, Jiang, Zhengjing, Lu, Lude
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967850/
https://www.ncbi.nlm.nih.gov/pubmed/21581536
http://dx.doi.org/10.1107/S1600536808036593
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author Zhang, Weiguang
Jiang, Zhengjing
Lu, Lude
author_facet Zhang, Weiguang
Jiang, Zhengjing
Lu, Lude
author_sort Zhang, Weiguang
collection PubMed
description The asymmetric unit of the title compound, [Cd(C(10)H(8)N(2))(3)](ClO(4))(2)·0.5H(2)O, consists of one complex [Cd(bpy)(3)](2+) cation (bpy = 2,2′-bipyridine), two perchlorate anions and one water molecule with half-occupancy. The central cadmium(II) ion is bound to six N atoms from three bpy ligands in a distorted octa­hedral coordination, with Cd—N bond distances ranging from 2.304 (3) to 2.395 (2) Å.
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spelling pubmed-29678502010-12-30 Tris(2,2′-bipyridine-κ(2) N,N′)cadmium(II) bis­(perchlorate) hemihydrate Zhang, Weiguang Jiang, Zhengjing Lu, Lude Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cd(C(10)H(8)N(2))(3)](ClO(4))(2)·0.5H(2)O, consists of one complex [Cd(bpy)(3)](2+) cation (bpy = 2,2′-bipyridine), two perchlorate anions and one water molecule with half-occupancy. The central cadmium(II) ion is bound to six N atoms from three bpy ligands in a distorted octa­hedral coordination, with Cd—N bond distances ranging from 2.304 (3) to 2.395 (2) Å. International Union of Crystallography 2008-12-03 /pmc/articles/PMC2967850/ /pubmed/21581536 http://dx.doi.org/10.1107/S1600536808036593 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Weiguang
Jiang, Zhengjing
Lu, Lude
Tris(2,2′-bipyridine-κ(2) N,N′)cadmium(II) bis­(perchlorate) hemihydrate
title Tris(2,2′-bipyridine-κ(2) N,N′)cadmium(II) bis­(perchlorate) hemihydrate
title_full Tris(2,2′-bipyridine-κ(2) N,N′)cadmium(II) bis­(perchlorate) hemihydrate
title_fullStr Tris(2,2′-bipyridine-κ(2) N,N′)cadmium(II) bis­(perchlorate) hemihydrate
title_full_unstemmed Tris(2,2′-bipyridine-κ(2) N,N′)cadmium(II) bis­(perchlorate) hemihydrate
title_short Tris(2,2′-bipyridine-κ(2) N,N′)cadmium(II) bis­(perchlorate) hemihydrate
title_sort tris(2,2′-bipyridine-κ(2) n,n′)cadmium(ii) bis­(perchlorate) hemihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967850/
https://www.ncbi.nlm.nih.gov/pubmed/21581536
http://dx.doi.org/10.1107/S1600536808036593
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