Dichlorido{[2-(diphenyl­phosphino)phenyl­imino­meth­yl]ferrocene-κ(2) N,P}palladium(II) dichloro­methane hemi­solvate

There are two independent Pd(II) complex mol­ecules in the asymmetric unit of the title compound, [PdCl(2){Fe(C(5)H(5))(C(24)H(19)NP)}]·0.5CH(2)Cl(2). One ferrocenyl ring of one complex mol­ecule is disordered over two sites with half-occupancy for each component. Both Pd(II) cations adopt a distort...

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Detalles Bibliográficos
Autores principales: Liu, Huanyu, Shen, Dongsheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967851/
https://www.ncbi.nlm.nih.gov/pubmed/21581545
http://dx.doi.org/10.1107/S1600536808039949
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author Liu, Huanyu
Shen, Dongsheng
author_facet Liu, Huanyu
Shen, Dongsheng
author_sort Liu, Huanyu
collection PubMed
description There are two independent Pd(II) complex mol­ecules in the asymmetric unit of the title compound, [PdCl(2){Fe(C(5)H(5))(C(24)H(19)NP)}]·0.5CH(2)Cl(2). One ferrocenyl ring of one complex mol­ecule is disordered over two sites with half-occupancy for each component. Both Pd(II) cations adopt a distorted square-planar coordination geometry with a bidentate [2-(diphenyl­phosphino)phenyl­imino­meth­yl]ferrocene ligand and two chloride anions.
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spelling pubmed-29678512010-12-30 Dichlorido{[2-(diphenyl­phosphino)phenyl­imino­meth­yl]ferrocene-κ(2) N,P}palladium(II) dichloro­methane hemi­solvate Liu, Huanyu Shen, Dongsheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers There are two independent Pd(II) complex mol­ecules in the asymmetric unit of the title compound, [PdCl(2){Fe(C(5)H(5))(C(24)H(19)NP)}]·0.5CH(2)Cl(2). One ferrocenyl ring of one complex mol­ecule is disordered over two sites with half-occupancy for each component. Both Pd(II) cations adopt a distorted square-planar coordination geometry with a bidentate [2-(diphenyl­phosphino)phenyl­imino­meth­yl]ferrocene ligand and two chloride anions. International Union of Crystallography 2008-12-03 /pmc/articles/PMC2967851/ /pubmed/21581545 http://dx.doi.org/10.1107/S1600536808039949 Text en © Liu and Shen 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Huanyu
Shen, Dongsheng
Dichlorido{[2-(diphenyl­phosphino)phenyl­imino­meth­yl]ferrocene-κ(2) N,P}palladium(II) dichloro­methane hemi­solvate
title Dichlorido{[2-(diphenyl­phosphino)phenyl­imino­meth­yl]ferrocene-κ(2) N,P}palladium(II) dichloro­methane hemi­solvate
title_full Dichlorido{[2-(diphenyl­phosphino)phenyl­imino­meth­yl]ferrocene-κ(2) N,P}palladium(II) dichloro­methane hemi­solvate
title_fullStr Dichlorido{[2-(diphenyl­phosphino)phenyl­imino­meth­yl]ferrocene-κ(2) N,P}palladium(II) dichloro­methane hemi­solvate
title_full_unstemmed Dichlorido{[2-(diphenyl­phosphino)phenyl­imino­meth­yl]ferrocene-κ(2) N,P}palladium(II) dichloro­methane hemi­solvate
title_short Dichlorido{[2-(diphenyl­phosphino)phenyl­imino­meth­yl]ferrocene-κ(2) N,P}palladium(II) dichloro­methane hemi­solvate
title_sort dichlorido{[2-(diphenyl­phosphino)phenyl­imino­meth­yl]ferrocene-κ(2) n,p}palladium(ii) dichloro­methane hemi­solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967851/
https://www.ncbi.nlm.nih.gov/pubmed/21581545
http://dx.doi.org/10.1107/S1600536808039949
work_keys_str_mv AT liuhuanyu dichlorido2diphenylphosphinophenyliminomethylferrocenek2nppalladiumiidichloromethanehemisolvate
AT shendongsheng dichlorido2diphenylphosphinophenyliminomethylferrocenek2nppalladiumiidichloromethanehemisolvate

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