Dichlorido(di-2-pyridylamine)mercury(II)

In the mol­ecule of the title compound, [HgCl(2)(C(10)H(9)N(3))], the Hg(II) atom is four-coordinated in a distorted tetra­hedral configuration by two N atoms from the chelating di-2-pyridylamine ligand and by two Cl atoms. In the crystal structure, inter­molecular N—H⋯Cl hydrogen bonds link the mol...

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Detalles Bibliográficos
Autores principales: Yousefi, Mohammad, Allahgholi Ghasri, Mohammad Reza, Heidari, Amene, Amani, Vahid
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967852/
https://www.ncbi.nlm.nih.gov/pubmed/21581552
http://dx.doi.org/10.1107/S1600536808040294
Descripción
Sumario:In the mol­ecule of the title compound, [HgCl(2)(C(10)H(9)N(3))], the Hg(II) atom is four-coordinated in a distorted tetra­hedral configuration by two N atoms from the chelating di-2-pyridylamine ligand and by two Cl atoms. In the crystal structure, inter­molecular N—H⋯Cl hydrogen bonds link the mol­ecules into centrosymmetric dimers. There is a π–π contact between the pyridine rings [centroid–centroid distance = 3.896 (5) Å].

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