Cargando…
Dichlorido(di-2-pyridylamine)mercury(II)
In the molecule of the title compound, [HgCl(2)(C(10)H(9)N(3))], the Hg(II) atom is four-coordinated in a distorted tetrahedral configuration by two N atoms from the chelating di-2-pyridylamine ligand and by two Cl atoms. In the crystal structure, intermolecular N—H⋯Cl hydrogen bonds link the mol...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967852/ https://www.ncbi.nlm.nih.gov/pubmed/21581552 http://dx.doi.org/10.1107/S1600536808040294 |
_version_ | 1782189710021492736 |
---|---|
author | Yousefi, Mohammad Allahgholi Ghasri, Mohammad Reza Heidari, Amene Amani, Vahid |
author_facet | Yousefi, Mohammad Allahgholi Ghasri, Mohammad Reza Heidari, Amene Amani, Vahid |
author_sort | Yousefi, Mohammad |
collection | PubMed |
description | In the molecule of the title compound, [HgCl(2)(C(10)H(9)N(3))], the Hg(II) atom is four-coordinated in a distorted tetrahedral configuration by two N atoms from the chelating di-2-pyridylamine ligand and by two Cl atoms. In the crystal structure, intermolecular N—H⋯Cl hydrogen bonds link the molecules into centrosymmetric dimers. There is a π–π contact between the pyridine rings [centroid–centroid distance = 3.896 (5) Å]. |
format | Text |
id | pubmed-2967852 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29678522010-12-30 Dichlorido(di-2-pyridylamine)mercury(II) Yousefi, Mohammad Allahgholi Ghasri, Mohammad Reza Heidari, Amene Amani, Vahid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the molecule of the title compound, [HgCl(2)(C(10)H(9)N(3))], the Hg(II) atom is four-coordinated in a distorted tetrahedral configuration by two N atoms from the chelating di-2-pyridylamine ligand and by two Cl atoms. In the crystal structure, intermolecular N—H⋯Cl hydrogen bonds link the molecules into centrosymmetric dimers. There is a π–π contact between the pyridine rings [centroid–centroid distance = 3.896 (5) Å]. International Union of Crystallography 2008-12-06 /pmc/articles/PMC2967852/ /pubmed/21581552 http://dx.doi.org/10.1107/S1600536808040294 Text en © Yousefi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yousefi, Mohammad Allahgholi Ghasri, Mohammad Reza Heidari, Amene Amani, Vahid Dichlorido(di-2-pyridylamine)mercury(II) |
title | Dichlorido(di-2-pyridylamine)mercury(II) |
title_full | Dichlorido(di-2-pyridylamine)mercury(II) |
title_fullStr | Dichlorido(di-2-pyridylamine)mercury(II) |
title_full_unstemmed | Dichlorido(di-2-pyridylamine)mercury(II) |
title_short | Dichlorido(di-2-pyridylamine)mercury(II) |
title_sort | dichlorido(di-2-pyridylamine)mercury(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967852/ https://www.ncbi.nlm.nih.gov/pubmed/21581552 http://dx.doi.org/10.1107/S1600536808040294 |
work_keys_str_mv | AT yousefimohammad dichloridodi2pyridylaminemercuryii AT allahgholighasrimohammadreza dichloridodi2pyridylaminemercuryii AT heidariamene dichloridodi2pyridylaminemercuryii AT amanivahid dichloridodi2pyridylaminemercuryii |