2,3-Bis(2-methoxy­phen­yl)tetra­zolium-5-thiol­ate–acetone–dichloro­methane (1/0.4/0.1)

In the title compound, C(15)H(14)N(4)O(2)S·0.4C(3)H(6)O·0.1CH(2)Cl(2), two benzene rings in the ortho-meth­oxy dehydro­dithizone (omd) mol­ecule are twisted out of the tetra­zole plane with the meth­oxy groups in a cis orientation relative to the tetrazole backbone. The acetone is located on a speci...

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Detalles Bibliográficos
Autores principales: von Eschwege, Karel G., Muller, Alfred
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967854/
https://www.ncbi.nlm.nih.gov/pubmed/21581653
http://dx.doi.org/10.1107/S1600536808039731
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author von Eschwege, Karel G.
Muller, Alfred
author_facet von Eschwege, Karel G.
Muller, Alfred
author_sort von Eschwege, Karel G.
collection PubMed
description In the title compound, C(15)H(14)N(4)O(2)S·0.4C(3)H(6)O·0.1CH(2)Cl(2), two benzene rings in the ortho-meth­oxy dehydro­dithizone (omd) mol­ecule are twisted out of the tetra­zole plane with the meth­oxy groups in a cis orientation relative to the tetrazole backbone. The acetone is located on a special position. The dihedral angles formed by the benzene rings with the central five-membered ring are 63.14 (8) and 57.06 (6)°. In the crystal structure, the relatively short distance of 3.886 (3) Å between the centroids of benzene rings from two neighbouring omd mol­ecules indicate π–π stacking inter­actions.
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spelling pubmed-29678542010-12-30 2,3-Bis(2-methoxy­phen­yl)tetra­zolium-5-thiol­ate–acetone–dichloro­methane (1/0.4/0.1) von Eschwege, Karel G. Muller, Alfred Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(14)N(4)O(2)S·0.4C(3)H(6)O·0.1CH(2)Cl(2), two benzene rings in the ortho-meth­oxy dehydro­dithizone (omd) mol­ecule are twisted out of the tetra­zole plane with the meth­oxy groups in a cis orientation relative to the tetrazole backbone. The acetone is located on a special position. The dihedral angles formed by the benzene rings with the central five-membered ring are 63.14 (8) and 57.06 (6)°. In the crystal structure, the relatively short distance of 3.886 (3) Å between the centroids of benzene rings from two neighbouring omd mol­ecules indicate π–π stacking inter­actions. International Union of Crystallography 2008-12-03 /pmc/articles/PMC2967854/ /pubmed/21581653 http://dx.doi.org/10.1107/S1600536808039731 Text en © Eschwege and Muller 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
von Eschwege, Karel G.
Muller, Alfred
2,3-Bis(2-methoxy­phen­yl)tetra­zolium-5-thiol­ate–acetone–dichloro­methane (1/0.4/0.1)
title 2,3-Bis(2-methoxy­phen­yl)tetra­zolium-5-thiol­ate–acetone–dichloro­methane (1/0.4/0.1)
title_full 2,3-Bis(2-methoxy­phen­yl)tetra­zolium-5-thiol­ate–acetone–dichloro­methane (1/0.4/0.1)
title_fullStr 2,3-Bis(2-methoxy­phen­yl)tetra­zolium-5-thiol­ate–acetone–dichloro­methane (1/0.4/0.1)
title_full_unstemmed 2,3-Bis(2-methoxy­phen­yl)tetra­zolium-5-thiol­ate–acetone–dichloro­methane (1/0.4/0.1)
title_short 2,3-Bis(2-methoxy­phen­yl)tetra­zolium-5-thiol­ate–acetone–dichloro­methane (1/0.4/0.1)
title_sort 2,3-bis(2-methoxy­phen­yl)tetra­zolium-5-thiol­ate–acetone–dichloro­methane (1/0.4/0.1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967854/
https://www.ncbi.nlm.nih.gov/pubmed/21581653
http://dx.doi.org/10.1107/S1600536808039731
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AT mulleralfred 23bis2methoxyphenyltetrazolium5thiolateacetonedichloromethane10401

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