Bis(1-ferrocenylethanone oximato)triphenyl­anti­mony(V)

In the title compound, [Fe(2)Sb(C(5)H(5))(2)(C(6)H(5))(3)(C(7)H(7)NO)(2)] or [Sb(C(6)H(5))(3){Fe(C(5)H(5))(C(7)H(7)NO)}(2)], the Sb center has a slightly distorted trigonal-bipyramidal geometry, with the three phenyl ligands in equatorial positions and the two O atoms from the ferrocenylethanone oxi...

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Detalles Bibliográficos
Autor principal: Fan, Jinshi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967863/
https://www.ncbi.nlm.nih.gov/pubmed/21581484
http://dx.doi.org/10.1107/S1600536808039834
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author Fan, Jinshi
author_facet Fan, Jinshi
author_sort Fan, Jinshi
collection PubMed
description In the title compound, [Fe(2)Sb(C(5)H(5))(2)(C(6)H(5))(3)(C(7)H(7)NO)(2)] or [Sb(C(6)H(5))(3){Fe(C(5)H(5))(C(7)H(7)NO)}(2)], the Sb center has a slightly distorted trigonal-bipyramidal geometry, with the three phenyl ligands in equatorial positions and the two O atoms from the ferrocenylethanone oximate ligands in axial positions. The crystal structure is stabilized by two inter­molecular C—H⋯π inter­actions.
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spelling pubmed-29678632010-12-30 Bis(1-ferrocenylethanone oximato)triphenyl­anti­mony(V) Fan, Jinshi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(2)Sb(C(5)H(5))(2)(C(6)H(5))(3)(C(7)H(7)NO)(2)] or [Sb(C(6)H(5))(3){Fe(C(5)H(5))(C(7)H(7)NO)}(2)], the Sb center has a slightly distorted trigonal-bipyramidal geometry, with the three phenyl ligands in equatorial positions and the two O atoms from the ferrocenylethanone oximate ligands in axial positions. The crystal structure is stabilized by two inter­molecular C—H⋯π inter­actions. International Union of Crystallography 2008-12-06 /pmc/articles/PMC2967863/ /pubmed/21581484 http://dx.doi.org/10.1107/S1600536808039834 Text en © Jinshi Fan 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fan, Jinshi
Bis(1-ferrocenylethanone oximato)triphenyl­anti­mony(V)
title Bis(1-ferrocenylethanone oximato)triphenyl­anti­mony(V)
title_full Bis(1-ferrocenylethanone oximato)triphenyl­anti­mony(V)
title_fullStr Bis(1-ferrocenylethanone oximato)triphenyl­anti­mony(V)
title_full_unstemmed Bis(1-ferrocenylethanone oximato)triphenyl­anti­mony(V)
title_short Bis(1-ferrocenylethanone oximato)triphenyl­anti­mony(V)
title_sort bis(1-ferrocenylethanone oximato)triphenyl­anti­mony(v)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967863/
https://www.ncbi.nlm.nih.gov/pubmed/21581484
http://dx.doi.org/10.1107/S1600536808039834
work_keys_str_mv AT fanjinshi bis1ferrocenylethanoneoximatotriphenylantimonyv

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