Bis[4-(dimethyl­amino)pyridinium] 3.75-bromido-0.25-chloridodiphenyl­plumbate(IV)

The Pb(IV) atom of the plumbate dianion in the title compound, (C(7)H(11)N)(2)[Pb(Br(3.75)Cl(0.25))(C(6)H(5))(2)], lies on a centre of inversion in a tetra­gonally compressed octa­hedral geometry. One of the attached Br atoms is disordered with respect to a Cl atom in a 7:1 ratio. The disordered hal...

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Detalles Bibliográficos
Autores principales: Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967864/
https://www.ncbi.nlm.nih.gov/pubmed/21581489
http://dx.doi.org/10.1107/S1600536808040312
Descripción
Sumario:The Pb(IV) atom of the plumbate dianion in the title compound, (C(7)H(11)N)(2)[Pb(Br(3.75)Cl(0.25))(C(6)H(5))(2)], lies on a centre of inversion in a tetra­gonally compressed octa­hedral geometry. One of the attached Br atoms is disordered with respect to a Cl atom in a 7:1 ratio. The disordered halogen atom is an N—H⋯(Br/Cl) hydrogen-bond acceptor for the cation.

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