Bis[4-(dimethyl­amino)pyridinium] 3.75-bromido-0.25-chloridodiphenyl­plumbate(IV)

The Pb(IV) atom of the plumbate dianion in the title compound, (C(7)H(11)N)(2)[Pb(Br(3.75)Cl(0.25))(C(6)H(5))(2)], lies on a centre of inversion in a tetra­gonally compressed octa­hedral geometry. One of the attached Br atoms is disordered with respect to a Cl atom in a 7:1 ratio. The disordered hal...

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Detalles Bibliográficos
Autores principales: Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967864/
https://www.ncbi.nlm.nih.gov/pubmed/21581489
http://dx.doi.org/10.1107/S1600536808040312
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author Lo, Kong Mun
Ng, Seik Weng
author_facet Lo, Kong Mun
Ng, Seik Weng
author_sort Lo, Kong Mun
collection PubMed
description The Pb(IV) atom of the plumbate dianion in the title compound, (C(7)H(11)N)(2)[Pb(Br(3.75)Cl(0.25))(C(6)H(5))(2)], lies on a centre of inversion in a tetra­gonally compressed octa­hedral geometry. One of the attached Br atoms is disordered with respect to a Cl atom in a 7:1 ratio. The disordered halogen atom is an N—H⋯(Br/Cl) hydrogen-bond acceptor for the cation.
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spelling pubmed-29678642010-12-30 Bis[4-(dimethyl­amino)pyridinium] 3.75-bromido-0.25-chloridodiphenyl­plumbate(IV) Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pb(IV) atom of the plumbate dianion in the title compound, (C(7)H(11)N)(2)[Pb(Br(3.75)Cl(0.25))(C(6)H(5))(2)], lies on a centre of inversion in a tetra­gonally compressed octa­hedral geometry. One of the attached Br atoms is disordered with respect to a Cl atom in a 7:1 ratio. The disordered halogen atom is an N—H⋯(Br/Cl) hydrogen-bond acceptor for the cation. International Union of Crystallography 2008-12-06 /pmc/articles/PMC2967864/ /pubmed/21581489 http://dx.doi.org/10.1107/S1600536808040312 Text en © Lo and Ng 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lo, Kong Mun
Ng, Seik Weng
Bis[4-(dimethyl­amino)pyridinium] 3.75-bromido-0.25-chloridodiphenyl­plumbate(IV)
title Bis[4-(dimethyl­amino)pyridinium] 3.75-bromido-0.25-chloridodiphenyl­plumbate(IV)
title_full Bis[4-(dimethyl­amino)pyridinium] 3.75-bromido-0.25-chloridodiphenyl­plumbate(IV)
title_fullStr Bis[4-(dimethyl­amino)pyridinium] 3.75-bromido-0.25-chloridodiphenyl­plumbate(IV)
title_full_unstemmed Bis[4-(dimethyl­amino)pyridinium] 3.75-bromido-0.25-chloridodiphenyl­plumbate(IV)
title_short Bis[4-(dimethyl­amino)pyridinium] 3.75-bromido-0.25-chloridodiphenyl­plumbate(IV)
title_sort bis[4-(dimethyl­amino)pyridinium] 3.75-bromido-0.25-chloridodiphenyl­plumbate(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967864/
https://www.ncbi.nlm.nih.gov/pubmed/21581489
http://dx.doi.org/10.1107/S1600536808040312
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