catena-Poly[bis­[(1,10-phenanthroline)iron(II)]-bis­(μ-5-carboxy­benzene-1,3-dicarboxyl­ato)]

The asymmetric unit of the title compound, [Fe(C(9)H(4)O(6))(C(12)H(8)N(2))(H(2)O)](n), contains one Fe(II) cation, one 5-carboxy­benzene-1,3-dicarboxyl­ate dianion (Hbtc), one 1,10-phenanthroline (phen) ligand and one water mol­ecule. The Fe(II) centre displays a distorted octa­hedral geometry, bei...

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Detalles Bibliográficos
Autores principales: Cheng, Lin, Zhang, Ya-Wen, Sun, Yan-Yan, Wang, Jian-Quan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967865/
https://www.ncbi.nlm.nih.gov/pubmed/21581490
http://dx.doi.org/10.1107/S160053680804018X
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author Cheng, Lin
Zhang, Ya-Wen
Sun, Yan-Yan
Wang, Jian-Quan
author_facet Cheng, Lin
Zhang, Ya-Wen
Sun, Yan-Yan
Wang, Jian-Quan
author_sort Cheng, Lin
collection PubMed
description The asymmetric unit of the title compound, [Fe(C(9)H(4)O(6))(C(12)H(8)N(2))(H(2)O)](n), contains one Fe(II) cation, one 5-carboxy­benzene-1,3-dicarboxyl­ate dianion (Hbtc), one 1,10-phenanthroline (phen) ligand and one water mol­ecule. The Fe(II) centre displays a distorted octa­hedral geometry, being surrounded by one phen ligand, two μ(2)-O atoms of two carboxyl­ate groups from two Hbtc ligands, one O atom from one carboxyl­ate of another Hbtc ligand and one terminal water mol­ecule. One carboxyl­ate group ligates two Fe(II) cations in a μ(1,1) mode, while the other carboxyl­ate groups bonds to only one Fe atom. The crystal structure is stabilized by O—H⋯O hydrogen bonds.
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spelling pubmed-29678652010-12-30 catena-Poly[bis­[(1,10-phenanthroline)iron(II)]-bis­(μ-5-carboxy­benzene-1,3-dicarboxyl­ato)] Cheng, Lin Zhang, Ya-Wen Sun, Yan-Yan Wang, Jian-Quan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Fe(C(9)H(4)O(6))(C(12)H(8)N(2))(H(2)O)](n), contains one Fe(II) cation, one 5-carboxy­benzene-1,3-dicarboxyl­ate dianion (Hbtc), one 1,10-phenanthroline (phen) ligand and one water mol­ecule. The Fe(II) centre displays a distorted octa­hedral geometry, being surrounded by one phen ligand, two μ(2)-O atoms of two carboxyl­ate groups from two Hbtc ligands, one O atom from one carboxyl­ate of another Hbtc ligand and one terminal water mol­ecule. One carboxyl­ate group ligates two Fe(II) cations in a μ(1,1) mode, while the other carboxyl­ate groups bonds to only one Fe atom. The crystal structure is stabilized by O—H⋯O hydrogen bonds. International Union of Crystallography 2008-12-06 /pmc/articles/PMC2967865/ /pubmed/21581490 http://dx.doi.org/10.1107/S160053680804018X Text en © Cheng et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cheng, Lin
Zhang, Ya-Wen
Sun, Yan-Yan
Wang, Jian-Quan
catena-Poly[bis­[(1,10-phenanthroline)iron(II)]-bis­(μ-5-carboxy­benzene-1,3-dicarboxyl­ato)]
title catena-Poly[bis­[(1,10-phenanthroline)iron(II)]-bis­(μ-5-carboxy­benzene-1,3-dicarboxyl­ato)]
title_full catena-Poly[bis­[(1,10-phenanthroline)iron(II)]-bis­(μ-5-carboxy­benzene-1,3-dicarboxyl­ato)]
title_fullStr catena-Poly[bis­[(1,10-phenanthroline)iron(II)]-bis­(μ-5-carboxy­benzene-1,3-dicarboxyl­ato)]
title_full_unstemmed catena-Poly[bis­[(1,10-phenanthroline)iron(II)]-bis­(μ-5-carboxy­benzene-1,3-dicarboxyl­ato)]
title_short catena-Poly[bis­[(1,10-phenanthroline)iron(II)]-bis­(μ-5-carboxy­benzene-1,3-dicarboxyl­ato)]
title_sort catena-poly[bis­[(1,10-phenanthroline)iron(ii)]-bis­(μ-5-carboxy­benzene-1,3-dicarboxyl­ato)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967865/
https://www.ncbi.nlm.nih.gov/pubmed/21581490
http://dx.doi.org/10.1107/S160053680804018X
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