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Bis(μ-N,N′-di-3-pyridylpyridine-2,6-dicarboxamide)bis­[dichloridomercury(II)] N,N-dimethyl­formamide disolvate

The asymmetric unit of the binuclear title complex, [Hg(2)Cl(4)(C(17)H(13)N(5)O(2))(2)]·2C(3)H(7)NO, contains one-half of the centrosymmetric mol­ecule and one dimethyl­formamide solvent mol­ecule. The Hg(II) atom is four-coordinated by two N atoms from two ligands and two Cl atoms in a distorted te...

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Detalles Bibliográficos
Autores principales: Huang, Li-Hua, Wu, Jie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967866/
https://www.ncbi.nlm.nih.gov/pubmed/21581491
http://dx.doi.org/10.1107/S1600536808040269
Descripción
Sumario:The asymmetric unit of the binuclear title complex, [Hg(2)Cl(4)(C(17)H(13)N(5)O(2))(2)]·2C(3)H(7)NO, contains one-half of the centrosymmetric mol­ecule and one dimethyl­formamide solvent mol­ecule. The Hg(II) atom is four-coordinated by two N atoms from two ligands and two Cl atoms in a distorted tetra­hedral coordination geometry. Intra­molecular N—H⋯O hydrogen bonds may be effective in the stabilization of the structure. In the crystal structure, π–π contacts between pyridine rings [centroid-to-centroid distances 3.629 (3) and 3.595 (3) Å] may further stabilize the structure.