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Bis(μ-N,N′-di-3-pyridylpyridine-2,6-dicarboxamide)bis[dichloridomercury(II)] N,N-dimethylformamide disolvate
The asymmetric unit of the binuclear title complex, [Hg(2)Cl(4)(C(17)H(13)N(5)O(2))(2)]·2C(3)H(7)NO, contains one-half of the centrosymmetric molecule and one dimethylformamide solvent molecule. The Hg(II) atom is four-coordinated by two N atoms from two ligands and two Cl atoms in a distorted te...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967866/ https://www.ncbi.nlm.nih.gov/pubmed/21581491 http://dx.doi.org/10.1107/S1600536808040269 |
Sumario: | The asymmetric unit of the binuclear title complex, [Hg(2)Cl(4)(C(17)H(13)N(5)O(2))(2)]·2C(3)H(7)NO, contains one-half of the centrosymmetric molecule and one dimethylformamide solvent molecule. The Hg(II) atom is four-coordinated by two N atoms from two ligands and two Cl atoms in a distorted tetrahedral coordination geometry. Intramolecular N—H⋯O hydrogen bonds may be effective in the stabilization of the structure. In the crystal structure, π–π contacts between pyridine rings [centroid-to-centroid distances 3.629 (3) and 3.595 (3) Å] may further stabilize the structure. |
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