Bis(μ-N,N′-di-3-pyridylpyridine-2,6-dicarboxamide)bis­[dichloridomercury(II)] N,N-dimethyl­formamide disolvate

The asymmetric unit of the binuclear title complex, [Hg(2)Cl(4)(C(17)H(13)N(5)O(2))(2)]·2C(3)H(7)NO, contains one-half of the centrosymmetric mol­ecule and one dimethyl­formamide solvent mol­ecule. The Hg(II) atom is four-coordinated by two N atoms from two ligands and two Cl atoms in a distorted te...

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Detalles Bibliográficos
Autores principales: Huang, Li-Hua, Wu, Jie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967866/
https://www.ncbi.nlm.nih.gov/pubmed/21581491
http://dx.doi.org/10.1107/S1600536808040269
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author Huang, Li-Hua
Wu, Jie
author_facet Huang, Li-Hua
Wu, Jie
author_sort Huang, Li-Hua
collection PubMed
description The asymmetric unit of the binuclear title complex, [Hg(2)Cl(4)(C(17)H(13)N(5)O(2))(2)]·2C(3)H(7)NO, contains one-half of the centrosymmetric mol­ecule and one dimethyl­formamide solvent mol­ecule. The Hg(II) atom is four-coordinated by two N atoms from two ligands and two Cl atoms in a distorted tetra­hedral coordination geometry. Intra­molecular N—H⋯O hydrogen bonds may be effective in the stabilization of the structure. In the crystal structure, π–π contacts between pyridine rings [centroid-to-centroid distances 3.629 (3) and 3.595 (3) Å] may further stabilize the structure.
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spelling pubmed-29678662010-12-30 Bis(μ-N,N′-di-3-pyridylpyridine-2,6-dicarboxamide)bis­[dichloridomercury(II)] N,N-dimethyl­formamide disolvate Huang, Li-Hua Wu, Jie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the binuclear title complex, [Hg(2)Cl(4)(C(17)H(13)N(5)O(2))(2)]·2C(3)H(7)NO, contains one-half of the centrosymmetric mol­ecule and one dimethyl­formamide solvent mol­ecule. The Hg(II) atom is four-coordinated by two N atoms from two ligands and two Cl atoms in a distorted tetra­hedral coordination geometry. Intra­molecular N—H⋯O hydrogen bonds may be effective in the stabilization of the structure. In the crystal structure, π–π contacts between pyridine rings [centroid-to-centroid distances 3.629 (3) and 3.595 (3) Å] may further stabilize the structure. International Union of Crystallography 2008-12-06 /pmc/articles/PMC2967866/ /pubmed/21581491 http://dx.doi.org/10.1107/S1600536808040269 Text en © Huang and Wu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huang, Li-Hua
Wu, Jie
Bis(μ-N,N′-di-3-pyridylpyridine-2,6-dicarboxamide)bis­[dichloridomercury(II)] N,N-dimethyl­formamide disolvate
title Bis(μ-N,N′-di-3-pyridylpyridine-2,6-dicarboxamide)bis­[dichloridomercury(II)] N,N-dimethyl­formamide disolvate
title_full Bis(μ-N,N′-di-3-pyridylpyridine-2,6-dicarboxamide)bis­[dichloridomercury(II)] N,N-dimethyl­formamide disolvate
title_fullStr Bis(μ-N,N′-di-3-pyridylpyridine-2,6-dicarboxamide)bis­[dichloridomercury(II)] N,N-dimethyl­formamide disolvate
title_full_unstemmed Bis(μ-N,N′-di-3-pyridylpyridine-2,6-dicarboxamide)bis­[dichloridomercury(II)] N,N-dimethyl­formamide disolvate
title_short Bis(μ-N,N′-di-3-pyridylpyridine-2,6-dicarboxamide)bis­[dichloridomercury(II)] N,N-dimethyl­formamide disolvate
title_sort bis(μ-n,n′-di-3-pyridylpyridine-2,6-dicarboxamide)bis­[dichloridomercury(ii)] n,n-dimethyl­formamide disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967866/
https://www.ncbi.nlm.nih.gov/pubmed/21581491
http://dx.doi.org/10.1107/S1600536808040269
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AT wujie bismnndi3pyridylpyridine26dicarboxamidebisdichloridomercuryiinndimethylformamidedisolvate

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