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Poly[ethylenediaminium [di-μ-aqua-(μ(6)-benzene-1,2,4,5-tetracarboxylato-κ(10) O (1),O (1′):O (2),O (2′):O (2′):O (4),O (4′):O (5):O (5),O (5′))dithallium(I)]]
The title compound, {(C(2)H(10)N(2))[Tl(2)(C(10)H(2)O(8))(H(2)O)(2))]}(n), was prepared using (enH(2))(2)(btc)·2H(2)O and thallium(I) nitrate (en = ethylenediamine and btcH(4) = benzene-1,2,4,5-tetracarboxylic acid). The enH(2) cation and btc ligand are each located on an inversion centre. The Tl(...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967867/ https://www.ncbi.nlm.nih.gov/pubmed/21581492 http://dx.doi.org/10.1107/S1600536808040282 |
| _version_ | 1782189713730306048 |
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| author | Rafizadeh, Masoud Manteghi, Faranak |
| author_facet | Rafizadeh, Masoud Manteghi, Faranak |
| author_sort | Rafizadeh, Masoud |
| collection | PubMed |
| description | The title compound, {(C(2)H(10)N(2))[Tl(2)(C(10)H(2)O(8))(H(2)O)(2))]}(n), was prepared using (enH(2))(2)(btc)·2H(2)O and thallium(I) nitrate (en = ethylenediamine and btcH(4) = benzene-1,2,4,5-tetracarboxylic acid). The enH(2) cation and btc ligand are each located on an inversion centre. The Tl(I) atom is seven-coordinated by three btc ligands and two water molecules in an irregular geometry due to the stereochemically active lone pair on the Tl centre. The water molecule and btc ligand are bonded to the Tl atoms in μ- and μ(6)-forms, respectively, leading to a three-dimensional structure. The crystal structure involves O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds, and also a Tl⋯π interaction of 3.537 (1) Å. |
| format | Text |
| id | pubmed-2967867 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29678672010-12-30 Poly[ethylenediaminium [di-μ-aqua-(μ(6)-benzene-1,2,4,5-tetracarboxylato-κ(10) O (1),O (1′):O (2),O (2′):O (2′):O (4),O (4′):O (5):O (5),O (5′))dithallium(I)]] Rafizadeh, Masoud Manteghi, Faranak Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {(C(2)H(10)N(2))[Tl(2)(C(10)H(2)O(8))(H(2)O)(2))]}(n), was prepared using (enH(2))(2)(btc)·2H(2)O and thallium(I) nitrate (en = ethylenediamine and btcH(4) = benzene-1,2,4,5-tetracarboxylic acid). The enH(2) cation and btc ligand are each located on an inversion centre. The Tl(I) atom is seven-coordinated by three btc ligands and two water molecules in an irregular geometry due to the stereochemically active lone pair on the Tl centre. The water molecule and btc ligand are bonded to the Tl atoms in μ- and μ(6)-forms, respectively, leading to a three-dimensional structure. The crystal structure involves O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds, and also a Tl⋯π interaction of 3.537 (1) Å. International Union of Crystallography 2008-12-06 /pmc/articles/PMC2967867/ /pubmed/21581492 http://dx.doi.org/10.1107/S1600536808040282 Text en © Rafizadeh and Manteghi 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Rafizadeh, Masoud Manteghi, Faranak Poly[ethylenediaminium [di-μ-aqua-(μ(6)-benzene-1,2,4,5-tetracarboxylato-κ(10) O (1),O (1′):O (2),O (2′):O (2′):O (4),O (4′):O (5):O (5),O (5′))dithallium(I)]] |
| title | Poly[ethylenediaminium [di-μ-aqua-(μ(6)-benzene-1,2,4,5-tetracarboxylato-κ(10)
O
(1),O
(1′):O
(2),O
(2′):O
(2′):O
(4),O
(4′):O
(5):O
(5),O
(5′))dithallium(I)]] |
| title_full | Poly[ethylenediaminium [di-μ-aqua-(μ(6)-benzene-1,2,4,5-tetracarboxylato-κ(10)
O
(1),O
(1′):O
(2),O
(2′):O
(2′):O
(4),O
(4′):O
(5):O
(5),O
(5′))dithallium(I)]] |
| title_fullStr | Poly[ethylenediaminium [di-μ-aqua-(μ(6)-benzene-1,2,4,5-tetracarboxylato-κ(10)
O
(1),O
(1′):O
(2),O
(2′):O
(2′):O
(4),O
(4′):O
(5):O
(5),O
(5′))dithallium(I)]] |
| title_full_unstemmed | Poly[ethylenediaminium [di-μ-aqua-(μ(6)-benzene-1,2,4,5-tetracarboxylato-κ(10)
O
(1),O
(1′):O
(2),O
(2′):O
(2′):O
(4),O
(4′):O
(5):O
(5),O
(5′))dithallium(I)]] |
| title_short | Poly[ethylenediaminium [di-μ-aqua-(μ(6)-benzene-1,2,4,5-tetracarboxylato-κ(10)
O
(1),O
(1′):O
(2),O
(2′):O
(2′):O
(4),O
(4′):O
(5):O
(5),O
(5′))dithallium(I)]] |
| title_sort | poly[ethylenediaminium [di-μ-aqua-(μ(6)-benzene-1,2,4,5-tetracarboxylato-κ(10)
o
(1),o
(1′):o
(2),o
(2′):o
(2′):o
(4),o
(4′):o
(5):o
(5),o
(5′))dithallium(i)]] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967867/ https://www.ncbi.nlm.nih.gov/pubmed/21581492 http://dx.doi.org/10.1107/S1600536808040282 |
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