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Bis[glycinium(0.5+)] perrhenate

All the residues of the title compound, (C(2)H(5.5)NO(2))(2)[ReO(4)], are located in general crystallographic positions. The glycine mol­ecules have usual conformations [Rodrigues Matos Beja et al. (2006 ▶). Acta Cryst. C62, o71–o72] with the H atom of the carboxylate group half-occupied, thus beari...

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Detalles Bibliográficos
Autores principales: Rodrigues, V. H., Costa, M. M. R. R., Dekola, T., de Matos Gomes, E.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967868/
https://www.ncbi.nlm.nih.gov/pubmed/21581493
http://dx.doi.org/10.1107/S160053680803849X
Descripción
Sumario:All the residues of the title compound, (C(2)H(5.5)NO(2))(2)[ReO(4)], are located in general crystallographic positions. The glycine mol­ecules have usual conformations [Rodrigues Matos Beja et al. (2006 ▶). Acta Cryst. C62, o71–o72] with the H atom of the carboxylate group half-occupied, thus bearing a formal half-positive charge per molecule. The perrhenate anion has nearly ideal tetra­hedral geometry. A large number of strong hydrogen bonds give rise to the overall three-dimensional network. A two-dimensional network, parallel to (100), is made up of strong O—H⋯O hydrogen bonds with a donor acceptor distance of 2.445 (2) Å. A large number of weaker O—H⋯O and N—H⋯O hydrogen bonds consolidates the structure into an overall three-dimensional network.