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Bis[glycinium(0.5+)] perrhenate

All the residues of the title compound, (C(2)H(5.5)NO(2))(2)[ReO(4)], are located in general crystallographic positions. The glycine mol­ecules have usual conformations [Rodrigues Matos Beja et al. (2006 ▶). Acta Cryst. C62, o71–o72] with the H atom of the carboxylate group half-occupied, thus beari...

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Detalles Bibliográficos
Autores principales: Rodrigues, V. H., Costa, M. M. R. R., Dekola, T., de Matos Gomes, E.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967868/
https://www.ncbi.nlm.nih.gov/pubmed/21581493
http://dx.doi.org/10.1107/S160053680803849X
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author Rodrigues, V. H.
Costa, M. M. R. R.
Dekola, T.
de Matos Gomes, E.
author_facet Rodrigues, V. H.
Costa, M. M. R. R.
Dekola, T.
de Matos Gomes, E.
author_sort Rodrigues, V. H.
collection PubMed
description All the residues of the title compound, (C(2)H(5.5)NO(2))(2)[ReO(4)], are located in general crystallographic positions. The glycine mol­ecules have usual conformations [Rodrigues Matos Beja et al. (2006 ▶). Acta Cryst. C62, o71–o72] with the H atom of the carboxylate group half-occupied, thus bearing a formal half-positive charge per molecule. The perrhenate anion has nearly ideal tetra­hedral geometry. A large number of strong hydrogen bonds give rise to the overall three-dimensional network. A two-dimensional network, parallel to (100), is made up of strong O—H⋯O hydrogen bonds with a donor acceptor distance of 2.445 (2) Å. A large number of weaker O—H⋯O and N—H⋯O hydrogen bonds consolidates the structure into an overall three-dimensional network.
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spelling pubmed-29678682010-12-30 Bis[glycinium(0.5+)] perrhenate Rodrigues, V. H. Costa, M. M. R. R. Dekola, T. de Matos Gomes, E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers All the residues of the title compound, (C(2)H(5.5)NO(2))(2)[ReO(4)], are located in general crystallographic positions. The glycine mol­ecules have usual conformations [Rodrigues Matos Beja et al. (2006 ▶). Acta Cryst. C62, o71–o72] with the H atom of the carboxylate group half-occupied, thus bearing a formal half-positive charge per molecule. The perrhenate anion has nearly ideal tetra­hedral geometry. A large number of strong hydrogen bonds give rise to the overall three-dimensional network. A two-dimensional network, parallel to (100), is made up of strong O—H⋯O hydrogen bonds with a donor acceptor distance of 2.445 (2) Å. A large number of weaker O—H⋯O and N—H⋯O hydrogen bonds consolidates the structure into an overall three-dimensional network. International Union of Crystallography 2008-12-06 /pmc/articles/PMC2967868/ /pubmed/21581493 http://dx.doi.org/10.1107/S160053680803849X Text en © Rodrigues et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rodrigues, V. H.
Costa, M. M. R. R.
Dekola, T.
de Matos Gomes, E.
Bis[glycinium(0.5+)] perrhenate
title Bis[glycinium(0.5+)] perrhenate
title_full Bis[glycinium(0.5+)] perrhenate
title_fullStr Bis[glycinium(0.5+)] perrhenate
title_full_unstemmed Bis[glycinium(0.5+)] perrhenate
title_short Bis[glycinium(0.5+)] perrhenate
title_sort bis[glycinium(0.5+)] perrhenate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967868/
https://www.ncbi.nlm.nih.gov/pubmed/21581493
http://dx.doi.org/10.1107/S160053680803849X
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