Bis[μ-3-ethyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole]bis­[dichloridocopper(II)]

The asymmetric unit of the title compound, [Cu(2)Cl(4)(C(15)H(14)N(4))(2)], contains two halves of two centrosymmetric dinuclear mol­ecules, A and B. The conformations of the two crystallographically independent mol­ecules are slightly different: in A, the Cu⋯Cu separation is 4.174 (9) Å and the dih...

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Detalles Bibliográficos
Autores principales: Wang, Zuoxiang, Liu, Chunyi, Zhang, Xiaoming, Gong, Xiaoning
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967870/
https://www.ncbi.nlm.nih.gov/pubmed/21581496
http://dx.doi.org/10.1107/S160053680804035X
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author Wang, Zuoxiang
Liu, Chunyi
Zhang, Xiaoming
Gong, Xiaoning
author_facet Wang, Zuoxiang
Liu, Chunyi
Zhang, Xiaoming
Gong, Xiaoning
author_sort Wang, Zuoxiang
collection PubMed
description The asymmetric unit of the title compound, [Cu(2)Cl(4)(C(15)H(14)N(4))(2)], contains two halves of two centrosymmetric dinuclear mol­ecules, A and B. The conformations of the two crystallographically independent mol­ecules are slightly different: in A, the Cu⋯Cu separation is 4.174 (9) Å and the dihedral angle between the triazole and phenyl rings is 74.23 (11)°; these values are 4.137 (9) Å and 68.58 (13)°, respectively, in B. In each mol­ecule, the copper(II) ions have a distorted trigonal–bipyramidal coordination geometry with a CuCl(2)NN′N′′ chromophore. The crystal packing exhibits weak inter­molecular C—H⋯Cl inter­actions.
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spelling pubmed-29678702010-12-30 Bis[μ-3-ethyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole]bis­[dichloridocopper(II)] Wang, Zuoxiang Liu, Chunyi Zhang, Xiaoming Gong, Xiaoning Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cu(2)Cl(4)(C(15)H(14)N(4))(2)], contains two halves of two centrosymmetric dinuclear mol­ecules, A and B. The conformations of the two crystallographically independent mol­ecules are slightly different: in A, the Cu⋯Cu separation is 4.174 (9) Å and the dihedral angle between the triazole and phenyl rings is 74.23 (11)°; these values are 4.137 (9) Å and 68.58 (13)°, respectively, in B. In each mol­ecule, the copper(II) ions have a distorted trigonal–bipyramidal coordination geometry with a CuCl(2)NN′N′′ chromophore. The crystal packing exhibits weak inter­molecular C—H⋯Cl inter­actions. International Union of Crystallography 2008-12-06 /pmc/articles/PMC2967870/ /pubmed/21581496 http://dx.doi.org/10.1107/S160053680804035X Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Zuoxiang
Liu, Chunyi
Zhang, Xiaoming
Gong, Xiaoning
Bis[μ-3-ethyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole]bis­[dichloridocopper(II)]
title Bis[μ-3-ethyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole]bis­[dichloridocopper(II)]
title_full Bis[μ-3-ethyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole]bis­[dichloridocopper(II)]
title_fullStr Bis[μ-3-ethyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole]bis­[dichloridocopper(II)]
title_full_unstemmed Bis[μ-3-ethyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole]bis­[dichloridocopper(II)]
title_short Bis[μ-3-ethyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole]bis­[dichloridocopper(II)]
title_sort bis[μ-3-ethyl-4-phenyl-5-(2-pyrid­yl)-4h-1,2,4-triazole]bis­[dichloridocopper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967870/
https://www.ncbi.nlm.nih.gov/pubmed/21581496
http://dx.doi.org/10.1107/S160053680804035X
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AT liuchunyi bism3ethyl4phenyl52pyridyl4h124triazolebisdichloridocopperii
AT zhangxiaoming bism3ethyl4phenyl52pyridyl4h124triazolebisdichloridocopperii
AT gongxiaoning bism3ethyl4phenyl52pyridyl4h124triazolebisdichloridocopperii

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