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trans-Dimethanolbis(1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)zinc(II)
The title compound, [Zn(C(8)H(10)F(3)O(2))(2)(CH(4)O)(2)], is a dimethanol coordinated zinc complex with the acetyl acetonate derivative 1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionate. The bis-β-diketonate complex, which is isostructural with its Co analogue, is located on a crystallographic inver...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967872/ https://www.ncbi.nlm.nih.gov/pubmed/21581498 http://dx.doi.org/10.1107/S1600536808037963 |
Sumario: | The title compound, [Zn(C(8)H(10)F(3)O(2))(2)(CH(4)O)(2)], is a dimethanol coordinated zinc complex with the acetyl acetonate derivative 1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionate. The bis-β-diketonate complex, which is isostructural with its Co analogue, is located on a crystallographic inversion center. The complex is octahedral with basically no distortion, and the methanol molecules are in trans positions with respect to one another. The planes of the β-diketonate and the ZnO(4) unit are tilted by 18.64 (10)° against each other. O—H⋯O hydrogen bonds between the methanol hydroxyl groups and neighboring diketonate O atoms create chains running along [100]. |
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