Cargando…

trans-Dimethano­lbis(1,1,1-trifluoro-5,5-dimethyl­hexane-2,4-dionato)zinc(II)

The title compound, [Zn(C(8)H(10)F(3)O(2))(2)(CH(4)O)(2)], is a dimethanol coordinated zinc complex with the acetyl acetonate derivative 1,1,1-trifluoro-5,5-dimethyl­hexane-2,4-dionate. The bis­-β-diketonate complex, which is isostructural with its Co analogue, is located on a crystallographic inver...

Descripción completa

Detalles Bibliográficos
Autores principales: Hunter, Gerald O., Zeller, Matthias, Leskiw, Brian D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967872/
https://www.ncbi.nlm.nih.gov/pubmed/21581498
http://dx.doi.org/10.1107/S1600536808037963
_version_ 1782189714915196928
author Hunter, Gerald O.
Zeller, Matthias
Leskiw, Brian D.
author_facet Hunter, Gerald O.
Zeller, Matthias
Leskiw, Brian D.
author_sort Hunter, Gerald O.
collection PubMed
description The title compound, [Zn(C(8)H(10)F(3)O(2))(2)(CH(4)O)(2)], is a dimethanol coordinated zinc complex with the acetyl acetonate derivative 1,1,1-trifluoro-5,5-dimethyl­hexane-2,4-dionate. The bis­-β-diketonate complex, which is isostructural with its Co analogue, is located on a crystallographic inversion center. The complex is octa­hedral with basically no distortion, and the methanol mol­ecules are in trans positions with respect to one another. The planes of the β-diketonate and the ZnO(4) unit are tilted by 18.64 (10)° against each other. O—H⋯O hydrogen bonds between the methanol hydroxyl groups and neighboring diketonate O atoms create chains running along [100].
format Text
id pubmed-2967872
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29678722010-12-30 trans-Dimethano­lbis(1,1,1-trifluoro-5,5-dimethyl­hexane-2,4-dionato)zinc(II) Hunter, Gerald O. Zeller, Matthias Leskiw, Brian D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zn(C(8)H(10)F(3)O(2))(2)(CH(4)O)(2)], is a dimethanol coordinated zinc complex with the acetyl acetonate derivative 1,1,1-trifluoro-5,5-dimethyl­hexane-2,4-dionate. The bis­-β-diketonate complex, which is isostructural with its Co analogue, is located on a crystallographic inversion center. The complex is octa­hedral with basically no distortion, and the methanol mol­ecules are in trans positions with respect to one another. The planes of the β-diketonate and the ZnO(4) unit are tilted by 18.64 (10)° against each other. O—H⋯O hydrogen bonds between the methanol hydroxyl groups and neighboring diketonate O atoms create chains running along [100]. International Union of Crystallography 2008-12-10 /pmc/articles/PMC2967872/ /pubmed/21581498 http://dx.doi.org/10.1107/S1600536808037963 Text en © Hunter et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hunter, Gerald O.
Zeller, Matthias
Leskiw, Brian D.
trans-Dimethano­lbis(1,1,1-trifluoro-5,5-dimethyl­hexane-2,4-dionato)zinc(II)
title trans-Dimethano­lbis(1,1,1-trifluoro-5,5-dimethyl­hexane-2,4-dionato)zinc(II)
title_full trans-Dimethano­lbis(1,1,1-trifluoro-5,5-dimethyl­hexane-2,4-dionato)zinc(II)
title_fullStr trans-Dimethano­lbis(1,1,1-trifluoro-5,5-dimethyl­hexane-2,4-dionato)zinc(II)
title_full_unstemmed trans-Dimethano­lbis(1,1,1-trifluoro-5,5-dimethyl­hexane-2,4-dionato)zinc(II)
title_short trans-Dimethano­lbis(1,1,1-trifluoro-5,5-dimethyl­hexane-2,4-dionato)zinc(II)
title_sort trans-dimethano­lbis(1,1,1-trifluoro-5,5-dimethyl­hexane-2,4-dionato)zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967872/
https://www.ncbi.nlm.nih.gov/pubmed/21581498
http://dx.doi.org/10.1107/S1600536808037963
work_keys_str_mv AT huntergeraldo transdimethanolbis111trifluoro55dimethylhexane24dionatozincii
AT zellermatthias transdimethanolbis111trifluoro55dimethylhexane24dionatozincii
AT leskiwbriand transdimethanolbis111trifluoro55dimethylhexane24dionatozincii