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trans-Dimethanolbis(1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)zinc(II)
The title compound, [Zn(C(8)H(10)F(3)O(2))(2)(CH(4)O)(2)], is a dimethanol coordinated zinc complex with the acetyl acetonate derivative 1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionate. The bis-β-diketonate complex, which is isostructural with its Co analogue, is located on a crystallographic inver...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967872/ https://www.ncbi.nlm.nih.gov/pubmed/21581498 http://dx.doi.org/10.1107/S1600536808037963 |
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author | Hunter, Gerald O. Zeller, Matthias Leskiw, Brian D. |
author_facet | Hunter, Gerald O. Zeller, Matthias Leskiw, Brian D. |
author_sort | Hunter, Gerald O. |
collection | PubMed |
description | The title compound, [Zn(C(8)H(10)F(3)O(2))(2)(CH(4)O)(2)], is a dimethanol coordinated zinc complex with the acetyl acetonate derivative 1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionate. The bis-β-diketonate complex, which is isostructural with its Co analogue, is located on a crystallographic inversion center. The complex is octahedral with basically no distortion, and the methanol molecules are in trans positions with respect to one another. The planes of the β-diketonate and the ZnO(4) unit are tilted by 18.64 (10)° against each other. O—H⋯O hydrogen bonds between the methanol hydroxyl groups and neighboring diketonate O atoms create chains running along [100]. |
format | Text |
id | pubmed-2967872 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29678722010-12-30 trans-Dimethanolbis(1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)zinc(II) Hunter, Gerald O. Zeller, Matthias Leskiw, Brian D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zn(C(8)H(10)F(3)O(2))(2)(CH(4)O)(2)], is a dimethanol coordinated zinc complex with the acetyl acetonate derivative 1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionate. The bis-β-diketonate complex, which is isostructural with its Co analogue, is located on a crystallographic inversion center. The complex is octahedral with basically no distortion, and the methanol molecules are in trans positions with respect to one another. The planes of the β-diketonate and the ZnO(4) unit are tilted by 18.64 (10)° against each other. O—H⋯O hydrogen bonds between the methanol hydroxyl groups and neighboring diketonate O atoms create chains running along [100]. International Union of Crystallography 2008-12-10 /pmc/articles/PMC2967872/ /pubmed/21581498 http://dx.doi.org/10.1107/S1600536808037963 Text en © Hunter et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hunter, Gerald O. Zeller, Matthias Leskiw, Brian D. trans-Dimethanolbis(1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)zinc(II) |
title |
trans-Dimethanolbis(1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)zinc(II) |
title_full |
trans-Dimethanolbis(1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)zinc(II) |
title_fullStr |
trans-Dimethanolbis(1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)zinc(II) |
title_full_unstemmed |
trans-Dimethanolbis(1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)zinc(II) |
title_short |
trans-Dimethanolbis(1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)zinc(II) |
title_sort | trans-dimethanolbis(1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)zinc(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967872/ https://www.ncbi.nlm.nih.gov/pubmed/21581498 http://dx.doi.org/10.1107/S1600536808037963 |
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