Di-μ-oxido-bis­({2-[(R,R)-(−)-(2-amino­cyclo­hexyl)imino­meth­yl]-4-nitro­phenolato-κ(3) N,N′,O}oxidovanadium(V)) dimethyl sulfoxide disolvate

The title compound, [V(2)(C(13)H(16)N(3)O(3))(2)O(4)]·2C(2)H(6)OS, is a centrosymmetric dimeric complex solvated by two dimethyl sulfoxide mol­ecules. Each V(V) atom is six-coordinated by one oxide group, two N atoms and one O atom from the tridentate Schiff base ligand, and by two additional bridgi...

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Autores principales: Romanowski, Grzegorz, Wera, Michał, Sikorski, Artur
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967873/
https://www.ncbi.nlm.nih.gov/pubmed/21581499
http://dx.doi.org/10.1107/S1600536808038762
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author Romanowski, Grzegorz
Wera, Michał
Sikorski, Artur
author_facet Romanowski, Grzegorz
Wera, Michał
Sikorski, Artur
author_sort Romanowski, Grzegorz
collection PubMed
description The title compound, [V(2)(C(13)H(16)N(3)O(3))(2)O(4)]·2C(2)H(6)OS, is a centrosymmetric dimeric complex solvated by two dimethyl sulfoxide mol­ecules. Each V(V) atom is six-coordinated by one oxide group, two N atoms and one O atom from the tridentate Schiff base ligand, and by two additional bridging O atoms in a distorted octa­hedral coordination geometry. Three atoms of the cyclo­hexane ring are each disordered over two sites, with occupancy factors of 0.501 (10) and 0.499 (10). C—H⋯O and N—H⋯O hydrogen bonds link the dimers and solvent mol­ecules into a supra­molecular network.
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spelling pubmed-29678732010-12-30 Di-μ-oxido-bis­({2-[(R,R)-(−)-(2-amino­cyclo­hexyl)imino­meth­yl]-4-nitro­phenolato-κ(3) N,N′,O}oxidovanadium(V)) dimethyl sulfoxide disolvate Romanowski, Grzegorz Wera, Michał Sikorski, Artur Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [V(2)(C(13)H(16)N(3)O(3))(2)O(4)]·2C(2)H(6)OS, is a centrosymmetric dimeric complex solvated by two dimethyl sulfoxide mol­ecules. Each V(V) atom is six-coordinated by one oxide group, two N atoms and one O atom from the tridentate Schiff base ligand, and by two additional bridging O atoms in a distorted octa­hedral coordination geometry. Three atoms of the cyclo­hexane ring are each disordered over two sites, with occupancy factors of 0.501 (10) and 0.499 (10). C—H⋯O and N—H⋯O hydrogen bonds link the dimers and solvent mol­ecules into a supra­molecular network. International Union of Crystallography 2008-12-10 /pmc/articles/PMC2967873/ /pubmed/21581499 http://dx.doi.org/10.1107/S1600536808038762 Text en © Romanowski et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Romanowski, Grzegorz
Wera, Michał
Sikorski, Artur
Di-μ-oxido-bis­({2-[(R,R)-(−)-(2-amino­cyclo­hexyl)imino­meth­yl]-4-nitro­phenolato-κ(3) N,N′,O}oxidovanadium(V)) dimethyl sulfoxide disolvate
title Di-μ-oxido-bis­({2-[(R,R)-(−)-(2-amino­cyclo­hexyl)imino­meth­yl]-4-nitro­phenolato-κ(3) N,N′,O}oxidovanadium(V)) dimethyl sulfoxide disolvate
title_full Di-μ-oxido-bis­({2-[(R,R)-(−)-(2-amino­cyclo­hexyl)imino­meth­yl]-4-nitro­phenolato-κ(3) N,N′,O}oxidovanadium(V)) dimethyl sulfoxide disolvate
title_fullStr Di-μ-oxido-bis­({2-[(R,R)-(−)-(2-amino­cyclo­hexyl)imino­meth­yl]-4-nitro­phenolato-κ(3) N,N′,O}oxidovanadium(V)) dimethyl sulfoxide disolvate
title_full_unstemmed Di-μ-oxido-bis­({2-[(R,R)-(−)-(2-amino­cyclo­hexyl)imino­meth­yl]-4-nitro­phenolato-κ(3) N,N′,O}oxidovanadium(V)) dimethyl sulfoxide disolvate
title_short Di-μ-oxido-bis­({2-[(R,R)-(−)-(2-amino­cyclo­hexyl)imino­meth­yl]-4-nitro­phenolato-κ(3) N,N′,O}oxidovanadium(V)) dimethyl sulfoxide disolvate
title_sort di-μ-oxido-bis­({2-[(r,r)-(−)-(2-amino­cyclo­hexyl)imino­meth­yl]-4-nitro­phenolato-κ(3) n,n′,o}oxidovanadium(v)) dimethyl sulfoxide disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967873/
https://www.ncbi.nlm.nih.gov/pubmed/21581499
http://dx.doi.org/10.1107/S1600536808038762
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AT weramichał dimoxidobis2rr2aminocyclohexyliminomethyl4nitrophenolatok3nnooxidovanadiumvdimethylsulfoxidedisolvate
AT sikorskiartur dimoxidobis2rr2aminocyclohexyliminomethyl4nitrophenolatok3nnooxidovanadiumvdimethylsulfoxidedisolvate

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