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Triaqua(2,2′-bipyridine)(5-nitroisophthalato-κO)nickel(II) monohydrate
In the title compound, [Ni(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)(3)]·H(2)O, the Ni(II) cation is six-coordinated by a chelating 2,2′-bipyridine ligand, one carboxylate O atom from a 5-nitroisophthalate dianion and three water molecules, with a slightly distorted cis-NiN(2)O(4) octahedral geometry...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967874/ https://www.ncbi.nlm.nih.gov/pubmed/21581500 http://dx.doi.org/10.1107/S1600536808038233 |
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author | Liu, Ying He, Qingpeng Zhang, Xianxi Xue, Zechun Lv, Chunyan |
author_facet | Liu, Ying He, Qingpeng Zhang, Xianxi Xue, Zechun Lv, Chunyan |
author_sort | Liu, Ying |
collection | PubMed |
description | In the title compound, [Ni(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)(3)]·H(2)O, the Ni(II) cation is six-coordinated by a chelating 2,2′-bipyridine ligand, one carboxylate O atom from a 5-nitroisophthalate dianion and three water molecules, with a slightly distorted cis-NiN(2)O(4) octahedral geometry. The neutral complex is isolated, in contrast to coordination polymers formed by Mn(II), Co(II) and Cu(II) with the same ligand set, but forms an extensive network of O—H⋯O hydrogen bonds between the coordinated and uncoordinated water molecules and carboxylate groups of the 5-nitroisophthalate ions. |
format | Text |
id | pubmed-2967874 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29678742010-12-30 Triaqua(2,2′-bipyridine)(5-nitroisophthalato-κO)nickel(II) monohydrate Liu, Ying He, Qingpeng Zhang, Xianxi Xue, Zechun Lv, Chunyan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)(3)]·H(2)O, the Ni(II) cation is six-coordinated by a chelating 2,2′-bipyridine ligand, one carboxylate O atom from a 5-nitroisophthalate dianion and three water molecules, with a slightly distorted cis-NiN(2)O(4) octahedral geometry. The neutral complex is isolated, in contrast to coordination polymers formed by Mn(II), Co(II) and Cu(II) with the same ligand set, but forms an extensive network of O—H⋯O hydrogen bonds between the coordinated and uncoordinated water molecules and carboxylate groups of the 5-nitroisophthalate ions. International Union of Crystallography 2008-12-10 /pmc/articles/PMC2967874/ /pubmed/21581500 http://dx.doi.org/10.1107/S1600536808038233 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Ying He, Qingpeng Zhang, Xianxi Xue, Zechun Lv, Chunyan Triaqua(2,2′-bipyridine)(5-nitroisophthalato-κO)nickel(II) monohydrate |
title | Triaqua(2,2′-bipyridine)(5-nitroisophthalato-κO)nickel(II) monohydrate |
title_full | Triaqua(2,2′-bipyridine)(5-nitroisophthalato-κO)nickel(II) monohydrate |
title_fullStr | Triaqua(2,2′-bipyridine)(5-nitroisophthalato-κO)nickel(II) monohydrate |
title_full_unstemmed | Triaqua(2,2′-bipyridine)(5-nitroisophthalato-κO)nickel(II) monohydrate |
title_short | Triaqua(2,2′-bipyridine)(5-nitroisophthalato-κO)nickel(II) monohydrate |
title_sort | triaqua(2,2′-bipyridine)(5-nitroisophthalato-κo)nickel(ii) monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967874/ https://www.ncbi.nlm.nih.gov/pubmed/21581500 http://dx.doi.org/10.1107/S1600536808038233 |
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