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Triaqua­(2,2′-bipyridine)(5-nitro­isophthal­ato-κO)nickel(II) monohydrate

In the title compound, [Ni(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)(3)]·H(2)O, the Ni(II) cation is six-coordinated by a chelating 2,2′-bipyridine ligand, one carboxyl­ate O atom from a 5-nitro­isophthalate dianion and three water mol­ecules, with a slightly distorted cis-NiN(2)O(4) octa­hedral geometry...

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Detalles Bibliográficos
Autores principales: Liu, Ying, He, Qingpeng, Zhang, Xianxi, Xue, Zechun, Lv, Chunyan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967874/
https://www.ncbi.nlm.nih.gov/pubmed/21581500
http://dx.doi.org/10.1107/S1600536808038233
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author Liu, Ying
He, Qingpeng
Zhang, Xianxi
Xue, Zechun
Lv, Chunyan
author_facet Liu, Ying
He, Qingpeng
Zhang, Xianxi
Xue, Zechun
Lv, Chunyan
author_sort Liu, Ying
collection PubMed
description In the title compound, [Ni(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)(3)]·H(2)O, the Ni(II) cation is six-coordinated by a chelating 2,2′-bipyridine ligand, one carboxyl­ate O atom from a 5-nitro­isophthalate dianion and three water mol­ecules, with a slightly distorted cis-NiN(2)O(4) octa­hedral geometry. The neutral complex is isolated, in contrast to coordination polymers formed by Mn(II), Co(II) and Cu(II) with the same ligand set, but forms an extensive network of O—H⋯O hydrogen bonds between the coordinated and uncoordinated water mol­ecules and carboxyl­ate groups of the 5-nitro­isophthalate ions.
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spelling pubmed-29678742010-12-30 Triaqua­(2,2′-bipyridine)(5-nitro­isophthal­ato-κO)nickel(II) monohydrate Liu, Ying He, Qingpeng Zhang, Xianxi Xue, Zechun Lv, Chunyan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)(3)]·H(2)O, the Ni(II) cation is six-coordinated by a chelating 2,2′-bipyridine ligand, one carboxyl­ate O atom from a 5-nitro­isophthalate dianion and three water mol­ecules, with a slightly distorted cis-NiN(2)O(4) octa­hedral geometry. The neutral complex is isolated, in contrast to coordination polymers formed by Mn(II), Co(II) and Cu(II) with the same ligand set, but forms an extensive network of O—H⋯O hydrogen bonds between the coordinated and uncoordinated water mol­ecules and carboxyl­ate groups of the 5-nitro­isophthalate ions. International Union of Crystallography 2008-12-10 /pmc/articles/PMC2967874/ /pubmed/21581500 http://dx.doi.org/10.1107/S1600536808038233 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Ying
He, Qingpeng
Zhang, Xianxi
Xue, Zechun
Lv, Chunyan
Triaqua­(2,2′-bipyridine)(5-nitro­isophthal­ato-κO)nickel(II) monohydrate
title Triaqua­(2,2′-bipyridine)(5-nitro­isophthal­ato-κO)nickel(II) monohydrate
title_full Triaqua­(2,2′-bipyridine)(5-nitro­isophthal­ato-κO)nickel(II) monohydrate
title_fullStr Triaqua­(2,2′-bipyridine)(5-nitro­isophthal­ato-κO)nickel(II) monohydrate
title_full_unstemmed Triaqua­(2,2′-bipyridine)(5-nitro­isophthal­ato-κO)nickel(II) monohydrate
title_short Triaqua­(2,2′-bipyridine)(5-nitro­isophthal­ato-κO)nickel(II) monohydrate
title_sort triaqua­(2,2′-bipyridine)(5-nitro­isophthal­ato-κo)nickel(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967874/
https://www.ncbi.nlm.nih.gov/pubmed/21581500
http://dx.doi.org/10.1107/S1600536808038233
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