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trans-N,N,N′,N′-Tetra­kis(carboxy­meth­yl)cyclo­hexane-1,2-diammonium tetra­chloridocadmium(II) tetra­hydrate

In the title compound, (C(14)H(24)N(2)O(8))[CdCl(4)]·4H(2)O, the Cd atom in the tetra­hedral [CdCl(4)](2−) anion lies on a twofold rotation axis, and the diprotonated organic mol­ecule, trans-N,N,N′,N′-tetra­kis(carb­oxy­meth­yl)cyclo­hexane-1,2-diammon­ium, has 2 symmetry with the twofold rotation...

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Detalles Bibliográficos
Autores principales: Lian, Ping, Hu, Qiao-Sheng, Xie, Yong-Rong, Guo, Hong-Xu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967879/
https://www.ncbi.nlm.nih.gov/pubmed/21581505
http://dx.doi.org/10.1107/S160053680804110X
Descripción
Sumario:In the title compound, (C(14)H(24)N(2)O(8))[CdCl(4)]·4H(2)O, the Cd atom in the tetra­hedral [CdCl(4)](2−) anion lies on a twofold rotation axis, and the diprotonated organic mol­ecule, trans-N,N,N′,N′-tetra­kis(carb­oxy­meth­yl)cyclo­hexane-1,2-diammon­ium, has 2 symmetry with the twofold rotation axis running through the mid-point of two C—C bonds in the cyclo­hexane unit. In the crystal structure, classical intra­molecular O—H⋯O and N—H⋯O and inter­molecular O—H⋯O, N—H⋯O, O—H⋯Cl and C—H⋯Cl hydrogen bonds are observed.