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trans-N,N,N′,N′-Tetra­kis(carboxy­meth­yl)cyclo­hexane-1,2-diammonium tetra­chloridocadmium(II) tetra­hydrate

In the title compound, (C(14)H(24)N(2)O(8))[CdCl(4)]·4H(2)O, the Cd atom in the tetra­hedral [CdCl(4)](2−) anion lies on a twofold rotation axis, and the diprotonated organic mol­ecule, trans-N,N,N′,N′-tetra­kis(carb­oxy­meth­yl)cyclo­hexane-1,2-diammon­ium, has 2 symmetry with the twofold rotation...

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Detalles Bibliográficos
Autores principales: Lian, Ping, Hu, Qiao-Sheng, Xie, Yong-Rong, Guo, Hong-Xu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967879/
https://www.ncbi.nlm.nih.gov/pubmed/21581505
http://dx.doi.org/10.1107/S160053680804110X
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author Lian, Ping
Hu, Qiao-Sheng
Xie, Yong-Rong
Guo, Hong-Xu
author_facet Lian, Ping
Hu, Qiao-Sheng
Xie, Yong-Rong
Guo, Hong-Xu
author_sort Lian, Ping
collection PubMed
description In the title compound, (C(14)H(24)N(2)O(8))[CdCl(4)]·4H(2)O, the Cd atom in the tetra­hedral [CdCl(4)](2−) anion lies on a twofold rotation axis, and the diprotonated organic mol­ecule, trans-N,N,N′,N′-tetra­kis(carb­oxy­meth­yl)cyclo­hexane-1,2-diammon­ium, has 2 symmetry with the twofold rotation axis running through the mid-point of two C—C bonds in the cyclo­hexane unit. In the crystal structure, classical intra­molecular O—H⋯O and N—H⋯O and inter­molecular O—H⋯O, N—H⋯O, O—H⋯Cl and C—H⋯Cl hydrogen bonds are observed.
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spelling pubmed-29678792010-12-30 trans-N,N,N′,N′-Tetra­kis(carboxy­meth­yl)cyclo­hexane-1,2-diammonium tetra­chloridocadmium(II) tetra­hydrate Lian, Ping Hu, Qiao-Sheng Xie, Yong-Rong Guo, Hong-Xu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(14)H(24)N(2)O(8))[CdCl(4)]·4H(2)O, the Cd atom in the tetra­hedral [CdCl(4)](2−) anion lies on a twofold rotation axis, and the diprotonated organic mol­ecule, trans-N,N,N′,N′-tetra­kis(carb­oxy­meth­yl)cyclo­hexane-1,2-diammon­ium, has 2 symmetry with the twofold rotation axis running through the mid-point of two C—C bonds in the cyclo­hexane unit. In the crystal structure, classical intra­molecular O—H⋯O and N—H⋯O and inter­molecular O—H⋯O, N—H⋯O, O—H⋯Cl and C—H⋯Cl hydrogen bonds are observed. International Union of Crystallography 2008-12-10 /pmc/articles/PMC2967879/ /pubmed/21581505 http://dx.doi.org/10.1107/S160053680804110X Text en © Lian et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lian, Ping
Hu, Qiao-Sheng
Xie, Yong-Rong
Guo, Hong-Xu
trans-N,N,N′,N′-Tetra­kis(carboxy­meth­yl)cyclo­hexane-1,2-diammonium tetra­chloridocadmium(II) tetra­hydrate
title trans-N,N,N′,N′-Tetra­kis(carboxy­meth­yl)cyclo­hexane-1,2-diammonium tetra­chloridocadmium(II) tetra­hydrate
title_full trans-N,N,N′,N′-Tetra­kis(carboxy­meth­yl)cyclo­hexane-1,2-diammonium tetra­chloridocadmium(II) tetra­hydrate
title_fullStr trans-N,N,N′,N′-Tetra­kis(carboxy­meth­yl)cyclo­hexane-1,2-diammonium tetra­chloridocadmium(II) tetra­hydrate
title_full_unstemmed trans-N,N,N′,N′-Tetra­kis(carboxy­meth­yl)cyclo­hexane-1,2-diammonium tetra­chloridocadmium(II) tetra­hydrate
title_short trans-N,N,N′,N′-Tetra­kis(carboxy­meth­yl)cyclo­hexane-1,2-diammonium tetra­chloridocadmium(II) tetra­hydrate
title_sort trans-n,n,n′,n′-tetra­kis(carboxy­meth­yl)cyclo­hexane-1,2-diammonium tetra­chloridocadmium(ii) tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967879/
https://www.ncbi.nlm.nih.gov/pubmed/21581505
http://dx.doi.org/10.1107/S160053680804110X
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