Cargando…
trans-N,N,N′,N′-Tetrakis(carboxymethyl)cyclohexane-1,2-diammonium tetrachloridocadmium(II) tetrahydrate
In the title compound, (C(14)H(24)N(2)O(8))[CdCl(4)]·4H(2)O, the Cd atom in the tetrahedral [CdCl(4)](2−) anion lies on a twofold rotation axis, and the diprotonated organic molecule, trans-N,N,N′,N′-tetrakis(carboxymethyl)cyclohexane-1,2-diammonium, has 2 symmetry with the twofold rotation...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967879/ https://www.ncbi.nlm.nih.gov/pubmed/21581505 http://dx.doi.org/10.1107/S160053680804110X |
_version_ | 1782189716565655552 |
---|---|
author | Lian, Ping Hu, Qiao-Sheng Xie, Yong-Rong Guo, Hong-Xu |
author_facet | Lian, Ping Hu, Qiao-Sheng Xie, Yong-Rong Guo, Hong-Xu |
author_sort | Lian, Ping |
collection | PubMed |
description | In the title compound, (C(14)H(24)N(2)O(8))[CdCl(4)]·4H(2)O, the Cd atom in the tetrahedral [CdCl(4)](2−) anion lies on a twofold rotation axis, and the diprotonated organic molecule, trans-N,N,N′,N′-tetrakis(carboxymethyl)cyclohexane-1,2-diammonium, has 2 symmetry with the twofold rotation axis running through the mid-point of two C—C bonds in the cyclohexane unit. In the crystal structure, classical intramolecular O—H⋯O and N—H⋯O and intermolecular O—H⋯O, N—H⋯O, O—H⋯Cl and C—H⋯Cl hydrogen bonds are observed. |
format | Text |
id | pubmed-2967879 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29678792010-12-30 trans-N,N,N′,N′-Tetrakis(carboxymethyl)cyclohexane-1,2-diammonium tetrachloridocadmium(II) tetrahydrate Lian, Ping Hu, Qiao-Sheng Xie, Yong-Rong Guo, Hong-Xu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(14)H(24)N(2)O(8))[CdCl(4)]·4H(2)O, the Cd atom in the tetrahedral [CdCl(4)](2−) anion lies on a twofold rotation axis, and the diprotonated organic molecule, trans-N,N,N′,N′-tetrakis(carboxymethyl)cyclohexane-1,2-diammonium, has 2 symmetry with the twofold rotation axis running through the mid-point of two C—C bonds in the cyclohexane unit. In the crystal structure, classical intramolecular O—H⋯O and N—H⋯O and intermolecular O—H⋯O, N—H⋯O, O—H⋯Cl and C—H⋯Cl hydrogen bonds are observed. International Union of Crystallography 2008-12-10 /pmc/articles/PMC2967879/ /pubmed/21581505 http://dx.doi.org/10.1107/S160053680804110X Text en © Lian et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Lian, Ping Hu, Qiao-Sheng Xie, Yong-Rong Guo, Hong-Xu trans-N,N,N′,N′-Tetrakis(carboxymethyl)cyclohexane-1,2-diammonium tetrachloridocadmium(II) tetrahydrate |
title |
trans-N,N,N′,N′-Tetrakis(carboxymethyl)cyclohexane-1,2-diammonium tetrachloridocadmium(II) tetrahydrate |
title_full |
trans-N,N,N′,N′-Tetrakis(carboxymethyl)cyclohexane-1,2-diammonium tetrachloridocadmium(II) tetrahydrate |
title_fullStr |
trans-N,N,N′,N′-Tetrakis(carboxymethyl)cyclohexane-1,2-diammonium tetrachloridocadmium(II) tetrahydrate |
title_full_unstemmed |
trans-N,N,N′,N′-Tetrakis(carboxymethyl)cyclohexane-1,2-diammonium tetrachloridocadmium(II) tetrahydrate |
title_short |
trans-N,N,N′,N′-Tetrakis(carboxymethyl)cyclohexane-1,2-diammonium tetrachloridocadmium(II) tetrahydrate |
title_sort | trans-n,n,n′,n′-tetrakis(carboxymethyl)cyclohexane-1,2-diammonium tetrachloridocadmium(ii) tetrahydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967879/ https://www.ncbi.nlm.nih.gov/pubmed/21581505 http://dx.doi.org/10.1107/S160053680804110X |
work_keys_str_mv | AT lianping transnnnntetrakiscarboxymethylcyclohexane12diammoniumtetrachloridocadmiumiitetrahydrate AT huqiaosheng transnnnntetrakiscarboxymethylcyclohexane12diammoniumtetrachloridocadmiumiitetrahydrate AT xieyongrong transnnnntetrakiscarboxymethylcyclohexane12diammoniumtetrachloridocadmiumiitetrahydrate AT guohongxu transnnnntetrakiscarboxymethylcyclohexane12diammoniumtetrachloridocadmiumiitetrahydrate |