catena-Poly[[(1,10-phenanthroline)cadmium(II)]-μ-2-(1,3-benzimidazol-2-ylsulfan­yl)acetato-κ(3) N (1),O:N (3)]

In title compound, [Cd(C(9)H(6)N(2)O(2)S)(C(12)H(8)N(2))](n), the Cd(II) atom is in a distorted tetra­gonal-pyramidal environment, coordinated by one chelating 1,10-phenanthroline ligand, one chelating 2-(1,3-benzimidazol-2-ylsulfan­yl)acetate (bia) ligand bound through one N atom and one O atom of...

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Detalles Bibliográficos
Autores principales: Cheng, Lin, Sun, Yan-Yan, Zhang, Ya-Wen, Wang, Jian-Quan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967880/
https://www.ncbi.nlm.nih.gov/pubmed/21581506
http://dx.doi.org/10.1107/S1600536808041044
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author Cheng, Lin
Sun, Yan-Yan
Zhang, Ya-Wen
Wang, Jian-Quan
author_facet Cheng, Lin
Sun, Yan-Yan
Zhang, Ya-Wen
Wang, Jian-Quan
author_sort Cheng, Lin
collection PubMed
description In title compound, [Cd(C(9)H(6)N(2)O(2)S)(C(12)H(8)N(2))](n), the Cd(II) atom is in a distorted tetra­gonal-pyramidal environment, coordinated by one chelating 1,10-phenanthroline ligand, one chelating 2-(1,3-benzimidazol-2-ylsulfan­yl)acetate (bia) ligand bound through one N atom and one O atom of the carboxyl group, and one N atom from a second bia ligand. Each bia ligand acts as bridge between Cd(II) ions, forming one-dimensional coordination polymers along [010], with a shortest Cd⋯Cd distance of 4.27 (2) Å.
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spelling pubmed-29678802010-12-30 catena-Poly[[(1,10-phenanthroline)cadmium(II)]-μ-2-(1,3-benzimidazol-2-ylsulfan­yl)acetato-κ(3) N (1),O:N (3)] Cheng, Lin Sun, Yan-Yan Zhang, Ya-Wen Wang, Jian-Quan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In title compound, [Cd(C(9)H(6)N(2)O(2)S)(C(12)H(8)N(2))](n), the Cd(II) atom is in a distorted tetra­gonal-pyramidal environment, coordinated by one chelating 1,10-phenanthroline ligand, one chelating 2-(1,3-benzimidazol-2-ylsulfan­yl)acetate (bia) ligand bound through one N atom and one O atom of the carboxyl group, and one N atom from a second bia ligand. Each bia ligand acts as bridge between Cd(II) ions, forming one-dimensional coordination polymers along [010], with a shortest Cd⋯Cd distance of 4.27 (2) Å. International Union of Crystallography 2008-12-10 /pmc/articles/PMC2967880/ /pubmed/21581506 http://dx.doi.org/10.1107/S1600536808041044 Text en © Cheng et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cheng, Lin
Sun, Yan-Yan
Zhang, Ya-Wen
Wang, Jian-Quan
catena-Poly[[(1,10-phenanthroline)cadmium(II)]-μ-2-(1,3-benzimidazol-2-ylsulfan­yl)acetato-κ(3) N (1),O:N (3)]
title catena-Poly[[(1,10-phenanthroline)cadmium(II)]-μ-2-(1,3-benzimidazol-2-ylsulfan­yl)acetato-κ(3) N (1),O:N (3)]
title_full catena-Poly[[(1,10-phenanthroline)cadmium(II)]-μ-2-(1,3-benzimidazol-2-ylsulfan­yl)acetato-κ(3) N (1),O:N (3)]
title_fullStr catena-Poly[[(1,10-phenanthroline)cadmium(II)]-μ-2-(1,3-benzimidazol-2-ylsulfan­yl)acetato-κ(3) N (1),O:N (3)]
title_full_unstemmed catena-Poly[[(1,10-phenanthroline)cadmium(II)]-μ-2-(1,3-benzimidazol-2-ylsulfan­yl)acetato-κ(3) N (1),O:N (3)]
title_short catena-Poly[[(1,10-phenanthroline)cadmium(II)]-μ-2-(1,3-benzimidazol-2-ylsulfan­yl)acetato-κ(3) N (1),O:N (3)]
title_sort catena-poly[[(1,10-phenanthroline)cadmium(ii)]-μ-2-(1,3-benzimidazol-2-ylsulfan­yl)acetato-κ(3) n (1),o:n (3)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967880/
https://www.ncbi.nlm.nih.gov/pubmed/21581506
http://dx.doi.org/10.1107/S1600536808041044
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