[4-Chloro-N′-(3-meth­oxy-2-oxidobenzyl­idene)benzohydrazidato]dimethyl­tin(IV)

In the title mol­ecule, [Sn(CH(3))(2)(C(15)H(11)ClN(2)O(3))], the two benzene rings form a dihedral angle of 6.37 (2)°. The Sn atom is coordinated by one N [Sn—N = 2.187 (3) Å], two O [Sn—O = 2.123 (3) and 2.174 (3) Å] and two C [Sn—C = 2.096 (4) and 2.101 (4) Å] atoms in a distorted trigonal-bipyra...

Descripción completa

Detalles Bibliográficos
Autores principales: Cui, Jichun, Qiao, Yanling, Yin, Handong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967882/
https://www.ncbi.nlm.nih.gov/pubmed/21581508
http://dx.doi.org/10.1107/S1600536808040786
Descripción
Sumario:In the title mol­ecule, [Sn(CH(3))(2)(C(15)H(11)ClN(2)O(3))], the two benzene rings form a dihedral angle of 6.37 (2)°. The Sn atom is coordinated by one N [Sn—N = 2.187 (3) Å], two O [Sn—O = 2.123 (3) and 2.174 (3) Å] and two C [Sn—C = 2.096 (4) and 2.101 (4) Å] atoms in a distorted trigonal-bipyramidal geometry. The crystal packing exhibits weak inter­molecular C—H⋯O hydrogen bonds, which link the mol­ecules into centrosymmetric dimers with an Sn⋯Sn separation of 4.330 (6) Å, and π–π inter­actions [centroid–centroid distance of 3.690 (5) Å between the benzene rings of neighbouring mol­ecules].

Ejemplares similares