[4-Chloro-N′-(3-meth­oxy-2-oxidobenzyl­idene)benzohydrazidato]dimethyl­tin(IV)

In the title mol­ecule, [Sn(CH(3))(2)(C(15)H(11)ClN(2)O(3))], the two benzene rings form a dihedral angle of 6.37 (2)°. The Sn atom is coordinated by one N [Sn—N = 2.187 (3) Å], two O [Sn—O = 2.123 (3) and 2.174 (3) Å] and two C [Sn—C = 2.096 (4) and 2.101 (4) Å] atoms in a distorted trigonal-bipyra...

Descripción completa

Detalles Bibliográficos
Autores principales: Cui, Jichun, Qiao, Yanling, Yin, Handong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967882/
https://www.ncbi.nlm.nih.gov/pubmed/21581508
http://dx.doi.org/10.1107/S1600536808040786
_version_ 1782189717301755904
author Cui, Jichun
Qiao, Yanling
Yin, Handong
author_facet Cui, Jichun
Qiao, Yanling
Yin, Handong
author_sort Cui, Jichun
collection PubMed
description In the title mol­ecule, [Sn(CH(3))(2)(C(15)H(11)ClN(2)O(3))], the two benzene rings form a dihedral angle of 6.37 (2)°. The Sn atom is coordinated by one N [Sn—N = 2.187 (3) Å], two O [Sn—O = 2.123 (3) and 2.174 (3) Å] and two C [Sn—C = 2.096 (4) and 2.101 (4) Å] atoms in a distorted trigonal-bipyramidal geometry. The crystal packing exhibits weak inter­molecular C—H⋯O hydrogen bonds, which link the mol­ecules into centrosymmetric dimers with an Sn⋯Sn separation of 4.330 (6) Å, and π–π inter­actions [centroid–centroid distance of 3.690 (5) Å between the benzene rings of neighbouring mol­ecules].
format Text
id pubmed-2967882
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29678822010-12-30 [4-Chloro-N′-(3-meth­oxy-2-oxidobenzyl­idene)benzohydrazidato]dimethyl­tin(IV) Cui, Jichun Qiao, Yanling Yin, Handong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mol­ecule, [Sn(CH(3))(2)(C(15)H(11)ClN(2)O(3))], the two benzene rings form a dihedral angle of 6.37 (2)°. The Sn atom is coordinated by one N [Sn—N = 2.187 (3) Å], two O [Sn—O = 2.123 (3) and 2.174 (3) Å] and two C [Sn—C = 2.096 (4) and 2.101 (4) Å] atoms in a distorted trigonal-bipyramidal geometry. The crystal packing exhibits weak inter­molecular C—H⋯O hydrogen bonds, which link the mol­ecules into centrosymmetric dimers with an Sn⋯Sn separation of 4.330 (6) Å, and π–π inter­actions [centroid–centroid distance of 3.690 (5) Å between the benzene rings of neighbouring mol­ecules]. International Union of Crystallography 2008-12-10 /pmc/articles/PMC2967882/ /pubmed/21581508 http://dx.doi.org/10.1107/S1600536808040786 Text en © Cui et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cui, Jichun
Qiao, Yanling
Yin, Handong
[4-Chloro-N′-(3-meth­oxy-2-oxidobenzyl­idene)benzohydrazidato]dimethyl­tin(IV)
title [4-Chloro-N′-(3-meth­oxy-2-oxidobenzyl­idene)benzohydrazidato]dimethyl­tin(IV)
title_full [4-Chloro-N′-(3-meth­oxy-2-oxidobenzyl­idene)benzohydrazidato]dimethyl­tin(IV)
title_fullStr [4-Chloro-N′-(3-meth­oxy-2-oxidobenzyl­idene)benzohydrazidato]dimethyl­tin(IV)
title_full_unstemmed [4-Chloro-N′-(3-meth­oxy-2-oxidobenzyl­idene)benzohydrazidato]dimethyl­tin(IV)
title_short [4-Chloro-N′-(3-meth­oxy-2-oxidobenzyl­idene)benzohydrazidato]dimethyl­tin(IV)
title_sort [4-chloro-n′-(3-meth­oxy-2-oxidobenzyl­idene)benzohydrazidato]dimethyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967882/
https://www.ncbi.nlm.nih.gov/pubmed/21581508
http://dx.doi.org/10.1107/S1600536808040786
work_keys_str_mv AT cuijichun 4chloron3methoxy2oxidobenzylidenebenzohydrazidatodimethyltiniv
AT qiaoyanling 4chloron3methoxy2oxidobenzylidenebenzohydrazidatodimethyltiniv
AT yinhandong 4chloron3methoxy2oxidobenzylidenebenzohydrazidatodimethyltiniv

Ejemplares similares