Di-μ-chlorido-bis­[(2,2′-bibenzimidazole)chloridocadmium(II)]

The title binuclear complex, [Cd(2)Cl(4)(C(14)H(10)N(4))(2)], was synthesized by the hydro­thermal reaction of CdCl(2) and the ligand 2,2′-bibenzimidazole. The mol­ecule lies on an inversion center and the metal center displays a strongly distorted trigonal-bipyramidal geometry. The Cd(II) ions are...

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Detalles Bibliográficos
Autor principal: Liu, Ge
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967883/
https://www.ncbi.nlm.nih.gov/pubmed/21581509
http://dx.doi.org/10.1107/S1600536808040968
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author Liu, Ge
author_facet Liu, Ge
author_sort Liu, Ge
collection PubMed
description The title binuclear complex, [Cd(2)Cl(4)(C(14)H(10)N(4))(2)], was synthesized by the hydro­thermal reaction of CdCl(2) and the ligand 2,2′-bibenzimidazole. The mol­ecule lies on an inversion center and the metal center displays a strongly distorted trigonal-bipyramidal geometry. The Cd(II) ions are coordinated by two N atoms from the organic ligand, and by one terminal and two bridging chloride anions. The crystal structure involves inter­molecular N—H⋯Cl hydrogen bonds, resulting in a one-dimensional supra­molecular structure.
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spelling pubmed-29678832010-12-30 Di-μ-chlorido-bis­[(2,2′-bibenzimidazole)chloridocadmium(II)] Liu, Ge Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title binuclear complex, [Cd(2)Cl(4)(C(14)H(10)N(4))(2)], was synthesized by the hydro­thermal reaction of CdCl(2) and the ligand 2,2′-bibenzimidazole. The mol­ecule lies on an inversion center and the metal center displays a strongly distorted trigonal-bipyramidal geometry. The Cd(II) ions are coordinated by two N atoms from the organic ligand, and by one terminal and two bridging chloride anions. The crystal structure involves inter­molecular N—H⋯Cl hydrogen bonds, resulting in a one-dimensional supra­molecular structure. International Union of Crystallography 2008-12-10 /pmc/articles/PMC2967883/ /pubmed/21581509 http://dx.doi.org/10.1107/S1600536808040968 Text en © Ge Liu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Ge
Di-μ-chlorido-bis­[(2,2′-bibenzimidazole)chloridocadmium(II)]
title Di-μ-chlorido-bis­[(2,2′-bibenzimidazole)chloridocadmium(II)]
title_full Di-μ-chlorido-bis­[(2,2′-bibenzimidazole)chloridocadmium(II)]
title_fullStr Di-μ-chlorido-bis­[(2,2′-bibenzimidazole)chloridocadmium(II)]
title_full_unstemmed Di-μ-chlorido-bis­[(2,2′-bibenzimidazole)chloridocadmium(II)]
title_short Di-μ-chlorido-bis­[(2,2′-bibenzimidazole)chloridocadmium(II)]
title_sort di-μ-chlorido-bis­[(2,2′-bibenzimidazole)chloridocadmium(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967883/
https://www.ncbi.nlm.nih.gov/pubmed/21581509
http://dx.doi.org/10.1107/S1600536808040968
work_keys_str_mv AT liuge dimchloridobis22bibenzimidazolechloridocadmiumii

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