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Dimethanolbis[N′-(3-pyridylmethylene)benzohydrazide]sodium(I) iodide
The molecule of the title compound, [Na(C(13)H(11)N(3)O)(2)(CH(3)OH)(2)]I, is non-planar, with the Na atom chelated by the O atoms and the N atoms of two N′-(3-pyridylmethylene)benzohydrazide ligands and both O atoms of two methanol ligands. The asymmetric unit consists of one half-molecule. The N...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967884/ https://www.ncbi.nlm.nih.gov/pubmed/21581510 http://dx.doi.org/10.1107/S1600536808040750 |
| _version_ | 1782189717774663680 |
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| author | Cui, Lian-Sheng Yin, Han-Dong Yang, Ming-Lei Wang, Da-Qi |
| author_facet | Cui, Lian-Sheng Yin, Han-Dong Yang, Ming-Lei Wang, Da-Qi |
| author_sort | Cui, Lian-Sheng |
| collection | PubMed |
| description | The molecule of the title compound, [Na(C(13)H(11)N(3)O)(2)(CH(3)OH)(2)]I, is non-planar, with the Na atom chelated by the O atoms and the N atoms of two N′-(3-pyridylmethylene)benzohydrazide ligands and both O atoms of two methanol ligands. The asymmetric unit consists of one half-molecule. The Na atom is located on a crystallographic centre of inversion. The six-coordinate Na atom adopts a distorted octahedral coordination. In the crystal structure, intermolecular N—H⋯I and O—H⋯N hydrogen bonds link the molecules into a two-dimensional network. |
| format | Text |
| id | pubmed-2967884 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29678842010-12-30 Dimethanolbis[N′-(3-pyridylmethylene)benzohydrazide]sodium(I) iodide Cui, Lian-Sheng Yin, Han-Dong Yang, Ming-Lei Wang, Da-Qi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The molecule of the title compound, [Na(C(13)H(11)N(3)O)(2)(CH(3)OH)(2)]I, is non-planar, with the Na atom chelated by the O atoms and the N atoms of two N′-(3-pyridylmethylene)benzohydrazide ligands and both O atoms of two methanol ligands. The asymmetric unit consists of one half-molecule. The Na atom is located on a crystallographic centre of inversion. The six-coordinate Na atom adopts a distorted octahedral coordination. In the crystal structure, intermolecular N—H⋯I and O—H⋯N hydrogen bonds link the molecules into a two-dimensional network. International Union of Crystallography 2008-12-10 /pmc/articles/PMC2967884/ /pubmed/21581510 http://dx.doi.org/10.1107/S1600536808040750 Text en © Cui et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Cui, Lian-Sheng Yin, Han-Dong Yang, Ming-Lei Wang, Da-Qi Dimethanolbis[N′-(3-pyridylmethylene)benzohydrazide]sodium(I) iodide |
| title | Dimethanolbis[N′-(3-pyridylmethylene)benzohydrazide]sodium(I) iodide |
| title_full | Dimethanolbis[N′-(3-pyridylmethylene)benzohydrazide]sodium(I) iodide |
| title_fullStr | Dimethanolbis[N′-(3-pyridylmethylene)benzohydrazide]sodium(I) iodide |
| title_full_unstemmed | Dimethanolbis[N′-(3-pyridylmethylene)benzohydrazide]sodium(I) iodide |
| title_short | Dimethanolbis[N′-(3-pyridylmethylene)benzohydrazide]sodium(I) iodide |
| title_sort | dimethanolbis[n′-(3-pyridylmethylene)benzohydrazide]sodium(i) iodide |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967884/ https://www.ncbi.nlm.nih.gov/pubmed/21581510 http://dx.doi.org/10.1107/S1600536808040750 |
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