μ-Nitrilo­triacetato-tris(1,10-phenanthroline)dizinc(II) nitrate hexa­hydrate

The nitrilo­triacetate trianion in the title compound, [Zn(2)(C(6)H(6)NO(6))(C(12)H(8)N(2))(3)]NO(3)·6H(2)O, is engaged in N,O,O′,O"-chelation to the phenanthroline-chelated Zn(II) unit, giving a distorted octa­hedral geometry for the metal atom. One of the three O atoms of the trianion that is...

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Detalles Bibliográficos
Autores principales: Chin, Lee Fang, Ng, Chew Hee, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967886/
https://www.ncbi.nlm.nih.gov/pubmed/21581513
http://dx.doi.org/10.1107/S1600536808041433
Descripción
Sumario:The nitrilo­triacetate trianion in the title compound, [Zn(2)(C(6)H(6)NO(6))(C(12)H(8)N(2))(3)]NO(3)·6H(2)O, is engaged in N,O,O′,O"-chelation to the phenanthroline-chelated Zn(II) unit, giving a distorted octa­hedral geometry for the metal atom. One of the three O atoms of the trianion that is engaged in chelation also binds to the bis­(phenanthroline)-chelated Zn(II) unit, whose five-coordinate geometry is distorted owing to a long Zn⋯O inter­action [2.401 (2) Å]. The dinuclear cations, nitrate anions and uncoordinated water mol­ecules are linked into a three-dimensional network via O—H⋯O hydrogen bonds between water molecules and carboxylate O atoms.

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