μ-Nitrilo­triacetato-tris(1,10-phenanthroline)dizinc(II) nitrate hexa­hydrate

The nitrilo­triacetate trianion in the title compound, [Zn(2)(C(6)H(6)NO(6))(C(12)H(8)N(2))(3)]NO(3)·6H(2)O, is engaged in N,O,O′,O"-chelation to the phenanthroline-chelated Zn(II) unit, giving a distorted octa­hedral geometry for the metal atom. One of the three O atoms of the trianion that is...

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Detalles Bibliográficos
Autores principales: Chin, Lee Fang, Ng, Chew Hee, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967886/
https://www.ncbi.nlm.nih.gov/pubmed/21581513
http://dx.doi.org/10.1107/S1600536808041433
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author Chin, Lee Fang
Ng, Chew Hee
Ng, Seik Weng
author_facet Chin, Lee Fang
Ng, Chew Hee
Ng, Seik Weng
author_sort Chin, Lee Fang
collection PubMed
description The nitrilo­triacetate trianion in the title compound, [Zn(2)(C(6)H(6)NO(6))(C(12)H(8)N(2))(3)]NO(3)·6H(2)O, is engaged in N,O,O′,O"-chelation to the phenanthroline-chelated Zn(II) unit, giving a distorted octa­hedral geometry for the metal atom. One of the three O atoms of the trianion that is engaged in chelation also binds to the bis­(phenanthroline)-chelated Zn(II) unit, whose five-coordinate geometry is distorted owing to a long Zn⋯O inter­action [2.401 (2) Å]. The dinuclear cations, nitrate anions and uncoordinated water mol­ecules are linked into a three-dimensional network via O—H⋯O hydrogen bonds between water molecules and carboxylate O atoms.
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spelling pubmed-29678862010-12-30 μ-Nitrilo­triacetato-tris(1,10-phenanthroline)dizinc(II) nitrate hexa­hydrate Chin, Lee Fang Ng, Chew Hee Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The nitrilo­triacetate trianion in the title compound, [Zn(2)(C(6)H(6)NO(6))(C(12)H(8)N(2))(3)]NO(3)·6H(2)O, is engaged in N,O,O′,O"-chelation to the phenanthroline-chelated Zn(II) unit, giving a distorted octa­hedral geometry for the metal atom. One of the three O atoms of the trianion that is engaged in chelation also binds to the bis­(phenanthroline)-chelated Zn(II) unit, whose five-coordinate geometry is distorted owing to a long Zn⋯O inter­action [2.401 (2) Å]. The dinuclear cations, nitrate anions and uncoordinated water mol­ecules are linked into a three-dimensional network via O—H⋯O hydrogen bonds between water molecules and carboxylate O atoms. International Union of Crystallography 2008-12-10 /pmc/articles/PMC2967886/ /pubmed/21581513 http://dx.doi.org/10.1107/S1600536808041433 Text en © Chin et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chin, Lee Fang
Ng, Chew Hee
Ng, Seik Weng
μ-Nitrilo­triacetato-tris(1,10-phenanthroline)dizinc(II) nitrate hexa­hydrate
title μ-Nitrilo­triacetato-tris(1,10-phenanthroline)dizinc(II) nitrate hexa­hydrate
title_full μ-Nitrilo­triacetato-tris(1,10-phenanthroline)dizinc(II) nitrate hexa­hydrate
title_fullStr μ-Nitrilo­triacetato-tris(1,10-phenanthroline)dizinc(II) nitrate hexa­hydrate
title_full_unstemmed μ-Nitrilo­triacetato-tris(1,10-phenanthroline)dizinc(II) nitrate hexa­hydrate
title_short μ-Nitrilo­triacetato-tris(1,10-phenanthroline)dizinc(II) nitrate hexa­hydrate
title_sort μ-nitrilo­triacetato-tris(1,10-phenanthroline)dizinc(ii) nitrate hexa­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967886/
https://www.ncbi.nlm.nih.gov/pubmed/21581513
http://dx.doi.org/10.1107/S1600536808041433
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