Aqua­(imino­diacetato-κ(3) O,N,O′)(1,10-phenanthroline-κ(2) N,N′)cobalt(II) monohydrate

The imino­diacetate dianion in the title compound, [Co(C(4)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)]·H(2)O, chelates to the cobalt(II) atom, its N and two O atoms occupying the fac sites of the distorted octa­hedron around the metal atom. The metal atom is also chelated by the N-heterocycle. The dianion, an...

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Detalles Bibliográficos
Autores principales: Ng, Hwa Loong, Ng, Chew Hee, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967887/
https://www.ncbi.nlm.nih.gov/pubmed/21581514
http://dx.doi.org/10.1107/S1600536808041226
Descripción
Sumario:The imino­diacetate dianion in the title compound, [Co(C(4)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)]·H(2)O, chelates to the cobalt(II) atom, its N and two O atoms occupying the fac sites of the distorted octa­hedron around the metal atom. The metal atom is also chelated by the N-heterocycle. The dianion, and coordinated and uncoordinated water mol­ecules inter­act through hydrogen bonds, generating a layer motif. The crystal studied was a racemic twin with a 0.62 (2):0.38 (2) domain ratio.

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