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Aqua(iminodiacetato-κ(3) O,N,O′)(1,10-phenanthroline-κ(2) N,N′)cobalt(II) monohydrate
The iminodiacetate dianion in the title compound, [Co(C(4)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)]·H(2)O, chelates to the cobalt(II) atom, its N and two O atoms occupying the fac sites of the distorted octahedron around the metal atom. The metal atom is also chelated by the N-heterocycle. The dianion, an...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967887/ https://www.ncbi.nlm.nih.gov/pubmed/21581514 http://dx.doi.org/10.1107/S1600536808041226 |
| _version_ | 1782189718498181120 |
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| author | Ng, Hwa Loong Ng, Chew Hee Ng, Seik Weng |
| author_facet | Ng, Hwa Loong Ng, Chew Hee Ng, Seik Weng |
| author_sort | Ng, Hwa Loong |
| collection | PubMed |
| description | The iminodiacetate dianion in the title compound, [Co(C(4)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)]·H(2)O, chelates to the cobalt(II) atom, its N and two O atoms occupying the fac sites of the distorted octahedron around the metal atom. The metal atom is also chelated by the N-heterocycle. The dianion, and coordinated and uncoordinated water molecules interact through hydrogen bonds, generating a layer motif. The crystal studied was a racemic twin with a 0.62 (2):0.38 (2) domain ratio. |
| format | Text |
| id | pubmed-2967887 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29678872010-12-30 Aqua(iminodiacetato-κ(3) O,N,O′)(1,10-phenanthroline-κ(2) N,N′)cobalt(II) monohydrate Ng, Hwa Loong Ng, Chew Hee Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The iminodiacetate dianion in the title compound, [Co(C(4)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)]·H(2)O, chelates to the cobalt(II) atom, its N and two O atoms occupying the fac sites of the distorted octahedron around the metal atom. The metal atom is also chelated by the N-heterocycle. The dianion, and coordinated and uncoordinated water molecules interact through hydrogen bonds, generating a layer motif. The crystal studied was a racemic twin with a 0.62 (2):0.38 (2) domain ratio. International Union of Crystallography 2008-12-10 /pmc/articles/PMC2967887/ /pubmed/21581514 http://dx.doi.org/10.1107/S1600536808041226 Text en © Ng et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ng, Hwa Loong Ng, Chew Hee Ng, Seik Weng Aqua(iminodiacetato-κ(3) O,N,O′)(1,10-phenanthroline-κ(2) N,N′)cobalt(II) monohydrate |
| title | Aqua(iminodiacetato-κ(3)
O,N,O′)(1,10-phenanthroline-κ(2)
N,N′)cobalt(II) monohydrate |
| title_full | Aqua(iminodiacetato-κ(3)
O,N,O′)(1,10-phenanthroline-κ(2)
N,N′)cobalt(II) monohydrate |
| title_fullStr | Aqua(iminodiacetato-κ(3)
O,N,O′)(1,10-phenanthroline-κ(2)
N,N′)cobalt(II) monohydrate |
| title_full_unstemmed | Aqua(iminodiacetato-κ(3)
O,N,O′)(1,10-phenanthroline-κ(2)
N,N′)cobalt(II) monohydrate |
| title_short | Aqua(iminodiacetato-κ(3)
O,N,O′)(1,10-phenanthroline-κ(2)
N,N′)cobalt(II) monohydrate |
| title_sort | aqua(iminodiacetato-κ(3)
o,n,o′)(1,10-phenanthroline-κ(2)
n,n′)cobalt(ii) monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967887/ https://www.ncbi.nlm.nih.gov/pubmed/21581514 http://dx.doi.org/10.1107/S1600536808041226 |
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