Chlorido{N,N′-o-phenyl­ene-[6,6′-ethyl­enebis(pyridine-2-carboxamide)]}iron(III)

In the title compound, [Fe(C(20)H(14)N(4)O(2))Cl], the Fe(III) ion is in a distorted square-pyramidal environment, with two pyridine and two deprotonated amide N atoms in the basal plane and the Cl ion in the apical position. The Fe(III) ion is displaced from the basal plane of the square- pyramid t...

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Detalles Bibliográficos
Autores principales: Yang, Li, Tang, Bin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967889/
https://www.ncbi.nlm.nih.gov/pubmed/21581516
http://dx.doi.org/10.1107/S1600536808041354
Descripción
Sumario:In the title compound, [Fe(C(20)H(14)N(4)O(2))Cl], the Fe(III) ion is in a distorted square-pyramidal environment, with two pyridine and two deprotonated amide N atoms in the basal plane and the Cl ion in the apical position. The Fe(III) ion is displaced from the basal plane of the square- pyramid towards the apical Cl atom by 0.2942 (4) Å. The mol­ecules are linked into a three-dimensional network by C—H⋯Cl and C—H⋯O hydrogen bonds.

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