Aquabis­(6-bromo­picolinato-κ(2) N,O)copper(II)

In the title compound, [Cu(C(6)H(3)BrNO(2))(2)(H(2)O)], the Cu atom adopts a distorted trigonal-bipyramidal coordination arising from two N,O-bidentate ligands and a water mol­ecule, with one N atom in an axial site and the other in an equatorial site. The dihedral angle between the pyridine ring pl...

Descripción completa

Detalles Bibliográficos
Autores principales: Hu, Fei-Long, Yue, Zhuang, Yan, Mi, Luo, Wei-Qiang, Yin, Xian-Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967890/
https://www.ncbi.nlm.nih.gov/pubmed/21581517
http://dx.doi.org/10.1107/S1600536808041536
Descripción
Sumario:In the title compound, [Cu(C(6)H(3)BrNO(2))(2)(H(2)O)], the Cu atom adopts a distorted trigonal-bipyramidal coordination arising from two N,O-bidentate ligands and a water mol­ecule, with one N atom in an axial site and the other in an equatorial site. The dihedral angle between the pyridine ring planes is 67.6 (2)°. In the crystal, O—H⋯O hydrogen bonds result in chains propagating in [100].

Ejemplares similares