Aquabis­(6-bromo­picolinato-κ(2) N,O)copper(II)

In the title compound, [Cu(C(6)H(3)BrNO(2))(2)(H(2)O)], the Cu atom adopts a distorted trigonal-bipyramidal coordination arising from two N,O-bidentate ligands and a water mol­ecule, with one N atom in an axial site and the other in an equatorial site. The dihedral angle between the pyridine ring pl...

Descripción completa

Detalles Bibliográficos
Autores principales: Hu, Fei-Long, Yue, Zhuang, Yan, Mi, Luo, Wei-Qiang, Yin, Xian-Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967890/
https://www.ncbi.nlm.nih.gov/pubmed/21581517
http://dx.doi.org/10.1107/S1600536808041536
_version_ 1782189719207018496
author Hu, Fei-Long
Yue, Zhuang
Yan, Mi
Luo, Wei-Qiang
Yin, Xian-Hong
author_facet Hu, Fei-Long
Yue, Zhuang
Yan, Mi
Luo, Wei-Qiang
Yin, Xian-Hong
author_sort Hu, Fei-Long
collection PubMed
description In the title compound, [Cu(C(6)H(3)BrNO(2))(2)(H(2)O)], the Cu atom adopts a distorted trigonal-bipyramidal coordination arising from two N,O-bidentate ligands and a water mol­ecule, with one N atom in an axial site and the other in an equatorial site. The dihedral angle between the pyridine ring planes is 67.6 (2)°. In the crystal, O—H⋯O hydrogen bonds result in chains propagating in [100].
format Text
id pubmed-2967890
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29678902010-12-30 Aquabis­(6-bromo­picolinato-κ(2) N,O)copper(II) Hu, Fei-Long Yue, Zhuang Yan, Mi Luo, Wei-Qiang Yin, Xian-Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(6)H(3)BrNO(2))(2)(H(2)O)], the Cu atom adopts a distorted trigonal-bipyramidal coordination arising from two N,O-bidentate ligands and a water mol­ecule, with one N atom in an axial site and the other in an equatorial site. The dihedral angle between the pyridine ring planes is 67.6 (2)°. In the crystal, O—H⋯O hydrogen bonds result in chains propagating in [100]. International Union of Crystallography 2008-12-10 /pmc/articles/PMC2967890/ /pubmed/21581517 http://dx.doi.org/10.1107/S1600536808041536 Text en © Hu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hu, Fei-Long
Yue, Zhuang
Yan, Mi
Luo, Wei-Qiang
Yin, Xian-Hong
Aquabis­(6-bromo­picolinato-κ(2) N,O)copper(II)
title Aquabis­(6-bromo­picolinato-κ(2) N,O)copper(II)
title_full Aquabis­(6-bromo­picolinato-κ(2) N,O)copper(II)
title_fullStr Aquabis­(6-bromo­picolinato-κ(2) N,O)copper(II)
title_full_unstemmed Aquabis­(6-bromo­picolinato-κ(2) N,O)copper(II)
title_short Aquabis­(6-bromo­picolinato-κ(2) N,O)copper(II)
title_sort aquabis­(6-bromo­picolinato-κ(2) n,o)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967890/
https://www.ncbi.nlm.nih.gov/pubmed/21581517
http://dx.doi.org/10.1107/S1600536808041536
work_keys_str_mv AT hufeilong aquabis6bromopicolinatok2nocopperii
AT yuezhuang aquabis6bromopicolinatok2nocopperii
AT yanmi aquabis6bromopicolinatok2nocopperii
AT luoweiqiang aquabis6bromopicolinatok2nocopperii
AT yinxianhong aquabis6bromopicolinatok2nocopperii

Ejemplares similares