Dimethyl 7a-carbonyl-2-meth­oxy-7a,7a-bis­(triphenyl­phosphino)-7a-ruthena-1-benzofuran-4,7-dicarboxyl­ate

The crystal structure of the title compound, [Ru(C(12)H(12)O(6))(C(18)H(15)P)(2)(CO)], confirms its formulation as a ruthenabenzofuran, with a slightly distorted octa­hedral coordination environment at the Ru(II) ion, and mutually trans triphenyl­phosphine ligands. The metallabicyclic ring system is...

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Detalles Bibliográficos
Autores principales: Clark, George R., Roper, Warren R., Tonei, Deborah M., Wright, L. James
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967895/
https://www.ncbi.nlm.nih.gov/pubmed/21581522
http://dx.doi.org/10.1107/S1600536808040944
Descripción
Sumario:The crystal structure of the title compound, [Ru(C(12)H(12)O(6))(C(18)H(15)P)(2)(CO)], confirms its formulation as a ruthenabenzofuran, with a slightly distorted octa­hedral coordination environment at the Ru(II) ion, and mutually trans triphenyl­phosphine ligands. The metallabicyclic ring system is essentially planar (maximum deviation 0.059 Å).

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