Dimethyl 7a-carbonyl-2-meth­oxy-7a,7a-bis­(triphenyl­phosphino)-7a-ruthena-1-benzofuran-4,7-dicarboxyl­ate

The crystal structure of the title compound, [Ru(C(12)H(12)O(6))(C(18)H(15)P)(2)(CO)], confirms its formulation as a ruthenabenzofuran, with a slightly distorted octa­hedral coordination environment at the Ru(II) ion, and mutually trans triphenyl­phosphine ligands. The metallabicyclic ring system is...

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Detalles Bibliográficos
Autores principales: Clark, George R., Roper, Warren R., Tonei, Deborah M., Wright, L. James
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967895/
https://www.ncbi.nlm.nih.gov/pubmed/21581522
http://dx.doi.org/10.1107/S1600536808040944
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author Clark, George R.
Roper, Warren R.
Tonei, Deborah M.
Wright, L. James
author_facet Clark, George R.
Roper, Warren R.
Tonei, Deborah M.
Wright, L. James
author_sort Clark, George R.
collection PubMed
description The crystal structure of the title compound, [Ru(C(12)H(12)O(6))(C(18)H(15)P)(2)(CO)], confirms its formulation as a ruthenabenzofuran, with a slightly distorted octa­hedral coordination environment at the Ru(II) ion, and mutually trans triphenyl­phosphine ligands. The metallabicyclic ring system is essentially planar (maximum deviation 0.059 Å).
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spelling pubmed-29678952010-12-30 Dimethyl 7a-carbonyl-2-meth­oxy-7a,7a-bis­(triphenyl­phosphino)-7a-ruthena-1-benzofuran-4,7-dicarboxyl­ate Clark, George R. Roper, Warren R. Tonei, Deborah M. Wright, L. James Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, [Ru(C(12)H(12)O(6))(C(18)H(15)P)(2)(CO)], confirms its formulation as a ruthenabenzofuran, with a slightly distorted octa­hedral coordination environment at the Ru(II) ion, and mutually trans triphenyl­phosphine ligands. The metallabicyclic ring system is essentially planar (maximum deviation 0.059 Å). International Union of Crystallography 2008-12-13 /pmc/articles/PMC2967895/ /pubmed/21581522 http://dx.doi.org/10.1107/S1600536808040944 Text en © Clark et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Clark, George R.
Roper, Warren R.
Tonei, Deborah M.
Wright, L. James
Dimethyl 7a-carbonyl-2-meth­oxy-7a,7a-bis­(triphenyl­phosphino)-7a-ruthena-1-benzofuran-4,7-dicarboxyl­ate
title Dimethyl 7a-carbonyl-2-meth­oxy-7a,7a-bis­(triphenyl­phosphino)-7a-ruthena-1-benzofuran-4,7-dicarboxyl­ate
title_full Dimethyl 7a-carbonyl-2-meth­oxy-7a,7a-bis­(triphenyl­phosphino)-7a-ruthena-1-benzofuran-4,7-dicarboxyl­ate
title_fullStr Dimethyl 7a-carbonyl-2-meth­oxy-7a,7a-bis­(triphenyl­phosphino)-7a-ruthena-1-benzofuran-4,7-dicarboxyl­ate
title_full_unstemmed Dimethyl 7a-carbonyl-2-meth­oxy-7a,7a-bis­(triphenyl­phosphino)-7a-ruthena-1-benzofuran-4,7-dicarboxyl­ate
title_short Dimethyl 7a-carbonyl-2-meth­oxy-7a,7a-bis­(triphenyl­phosphino)-7a-ruthena-1-benzofuran-4,7-dicarboxyl­ate
title_sort dimethyl 7a-carbonyl-2-meth­oxy-7a,7a-bis­(triphenyl­phosphino)-7a-ruthena-1-benzofuran-4,7-dicarboxyl­ate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967895/
https://www.ncbi.nlm.nih.gov/pubmed/21581522
http://dx.doi.org/10.1107/S1600536808040944
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AT toneideborahm dimethyl7acarbonyl2methoxy7a7abistriphenylphosphino7aruthena1benzofuran47dicarboxylate
AT wrightljames dimethyl7acarbonyl2methoxy7a7abistriphenylphosphino7aruthena1benzofuran47dicarboxylate

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