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Dichlorido(10,11,12,13-tetrahydro-4,5,9,14-tetraazabenzo[b]triphenylene)cadmium(II) hemihydrate
In the title compound, [CdCl(2)(C(18)H(14)N(4))(2)]·0.5H(2)O, the Cd atom assumes a distorted octahedral trans-CdCl(2)N(4) geometry arising from its coordination by two N,N′-bidentate 10,11,12,13-tetrahydro-4,5,9,14-tetraazabenzo[b]triphenylene (TBBT) molecules and two chloride ions. In the cry...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967896/ https://www.ncbi.nlm.nih.gov/pubmed/21581523 http://dx.doi.org/10.1107/S1600536808041305 |
| _version_ | 1782189720677122048 |
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| author | Li, Chun-Xiang Li, Xiu-Ying Liu, Chun-Bo Yan, Yong-Sheng Che, Guang-Bo |
| author_facet | Li, Chun-Xiang Li, Xiu-Ying Liu, Chun-Bo Yan, Yong-Sheng Che, Guang-Bo |
| author_sort | Li, Chun-Xiang |
| collection | PubMed |
| description | In the title compound, [CdCl(2)(C(18)H(14)N(4))(2)]·0.5H(2)O, the Cd atom assumes a distorted octahedral trans-CdCl(2)N(4) geometry arising from its coordination by two N,N′-bidentate 10,11,12,13-tetrahydro-4,5,9,14-tetraazabenzo[b]triphenylene (TBBT) molecules and two chloride ions. In the crystal, π–π aromatic stacking interactions between adjacent TTBT rings are seen, with a centroid–centroid distance of 3.604 (3) Å. An O—H⋯Cl hydrogen bond between the half-occupied water molecule and one chloride ion also occurs. |
| format | Text |
| id | pubmed-2967896 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29678962010-12-30 Dichlorido(10,11,12,13-tetrahydro-4,5,9,14-tetraazabenzo[b]triphenylene)cadmium(II) hemihydrate Li, Chun-Xiang Li, Xiu-Ying Liu, Chun-Bo Yan, Yong-Sheng Che, Guang-Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CdCl(2)(C(18)H(14)N(4))(2)]·0.5H(2)O, the Cd atom assumes a distorted octahedral trans-CdCl(2)N(4) geometry arising from its coordination by two N,N′-bidentate 10,11,12,13-tetrahydro-4,5,9,14-tetraazabenzo[b]triphenylene (TBBT) molecules and two chloride ions. In the crystal, π–π aromatic stacking interactions between adjacent TTBT rings are seen, with a centroid–centroid distance of 3.604 (3) Å. An O—H⋯Cl hydrogen bond between the half-occupied water molecule and one chloride ion also occurs. International Union of Crystallography 2008-12-13 /pmc/articles/PMC2967896/ /pubmed/21581523 http://dx.doi.org/10.1107/S1600536808041305 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Chun-Xiang Li, Xiu-Ying Liu, Chun-Bo Yan, Yong-Sheng Che, Guang-Bo Dichlorido(10,11,12,13-tetrahydro-4,5,9,14-tetraazabenzo[b]triphenylene)cadmium(II) hemihydrate |
| title | Dichlorido(10,11,12,13-tetrahydro-4,5,9,14-tetraazabenzo[b]triphenylene)cadmium(II) hemihydrate |
| title_full | Dichlorido(10,11,12,13-tetrahydro-4,5,9,14-tetraazabenzo[b]triphenylene)cadmium(II) hemihydrate |
| title_fullStr | Dichlorido(10,11,12,13-tetrahydro-4,5,9,14-tetraazabenzo[b]triphenylene)cadmium(II) hemihydrate |
| title_full_unstemmed | Dichlorido(10,11,12,13-tetrahydro-4,5,9,14-tetraazabenzo[b]triphenylene)cadmium(II) hemihydrate |
| title_short | Dichlorido(10,11,12,13-tetrahydro-4,5,9,14-tetraazabenzo[b]triphenylene)cadmium(II) hemihydrate |
| title_sort | dichlorido(10,11,12,13-tetrahydro-4,5,9,14-tetraazabenzo[b]triphenylene)cadmium(ii) hemihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967896/ https://www.ncbi.nlm.nih.gov/pubmed/21581523 http://dx.doi.org/10.1107/S1600536808041305 |
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