Bis(imidazo[4,5-f][1,10]phenanthroline)dinitratolead(II)

In the title compound, [Pb(NO(3))(2)(C(13)H(8)N(4))(2)], the Pb(II) atom (site symmetry 2) is hexa­coordinated by four N atoms from two N,N′-bidentate imidazo[4,5-f][1,10]phenanthroline (L) ligands and two O atoms from two weakly coordinated nitrate ions [Pb—O = 2.872 (5) Å] in an irregular arrangem...

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Autores principales: Li, Chun-Xiang, Zha, Xiao-Lin, Liu, Chun-Bo, Li, Xiu-Ying, Che, Guang-Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967897/
https://www.ncbi.nlm.nih.gov/pubmed/21581524
http://dx.doi.org/10.1107/S1600536808041317
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author Li, Chun-Xiang
Zha, Xiao-Lin
Liu, Chun-Bo
Li, Xiu-Ying
Che, Guang-Bo
author_facet Li, Chun-Xiang
Zha, Xiao-Lin
Liu, Chun-Bo
Li, Xiu-Ying
Che, Guang-Bo
author_sort Li, Chun-Xiang
collection PubMed
description In the title compound, [Pb(NO(3))(2)(C(13)H(8)N(4))(2)], the Pb(II) atom (site symmetry 2) is hexa­coordinated by four N atoms from two N,N′-bidentate imidazo[4,5-f][1,10]phenanthroline (L) ligands and two O atoms from two weakly coordinated nitrate ions [Pb—O = 2.872 (5) Å] in an irregular arrangement, which may be ascribed to the stereochemically active lone pair of electrons on the metal ion. In the crystal, inter­molecular bifurcated N—H⋯(O,O) hydrogen bonds connect the mol­ecules into chains propagating along [100]. Adjacent chains inter­act by strong aromatic π–π stacking inter­actions, with a centroid–centroid distance of 3.483 (2) Å.
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spelling pubmed-29678972010-12-30 Bis(imidazo[4,5-f][1,10]phenanthroline)dinitratolead(II) Li, Chun-Xiang Zha, Xiao-Lin Liu, Chun-Bo Li, Xiu-Ying Che, Guang-Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pb(NO(3))(2)(C(13)H(8)N(4))(2)], the Pb(II) atom (site symmetry 2) is hexa­coordinated by four N atoms from two N,N′-bidentate imidazo[4,5-f][1,10]phenanthroline (L) ligands and two O atoms from two weakly coordinated nitrate ions [Pb—O = 2.872 (5) Å] in an irregular arrangement, which may be ascribed to the stereochemically active lone pair of electrons on the metal ion. In the crystal, inter­molecular bifurcated N—H⋯(O,O) hydrogen bonds connect the mol­ecules into chains propagating along [100]. Adjacent chains inter­act by strong aromatic π–π stacking inter­actions, with a centroid–centroid distance of 3.483 (2) Å. International Union of Crystallography 2008-12-13 /pmc/articles/PMC2967897/ /pubmed/21581524 http://dx.doi.org/10.1107/S1600536808041317 Text en © Li* et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Chun-Xiang
Zha, Xiao-Lin
Liu, Chun-Bo
Li, Xiu-Ying
Che, Guang-Bo
Bis(imidazo[4,5-f][1,10]phenanthroline)dinitratolead(II)
title Bis(imidazo[4,5-f][1,10]phenanthroline)dinitratolead(II)
title_full Bis(imidazo[4,5-f][1,10]phenanthroline)dinitratolead(II)
title_fullStr Bis(imidazo[4,5-f][1,10]phenanthroline)dinitratolead(II)
title_full_unstemmed Bis(imidazo[4,5-f][1,10]phenanthroline)dinitratolead(II)
title_short Bis(imidazo[4,5-f][1,10]phenanthroline)dinitratolead(II)
title_sort bis(imidazo[4,5-f][1,10]phenanthroline)dinitratolead(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2967897/
https://www.ncbi.nlm.nih.gov/pubmed/21581524
http://dx.doi.org/10.1107/S1600536808041317
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